Crystal structure of a dinuclear nitrido-bridged ruthenium complex with pyridine ligands

Аннотация

A new dinuclear nitrido-bridged ruthenium complex with pyridine ligands ([PyH][Ru₂N(Py)₄Cl₆] (1) is synthesized by reacting K₃[Ru₂NCl₈(H₂O)2] (2) and excessive pyridine, then crystallized from dilute hydrochloric acid. Its crystal structure is determined by single crystal X-ray diffraction. The complex crystallizes in the form of red block crystals of the monoclinic symmetry and the space group C₂. The nitrido-bridged ruthenium complex has very short Ru–N distances.