Crystal structure of a dinuclear nitrido-bridged ruthenium complex with pyridine ligands

Q. W. Chang; C. X. Yan; J. Jiang; Q. S. Ye; J. Yu; J. L. Chen; H. Cui; W. P. Liu

doi:10.1134/S0022476617030295

Crystal structure of a dinuclear nitrido-bridged ruthenium complex with pyridine ligands

Authors: Chang Q.W.¹, Yan C.X.¹, Jiang J.¹, Ye Q.S.¹, Yu J.¹, Chen J.L.¹, Cui H.¹, Liu W.P.¹
Affiliations:
1. State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals
Issue: Vol 58, No 3 (2017)
Pages: 624-626
Section: Brief Communications
URL: https://journals.rcsi.science/0022-4766/article/view/161345
DOI: https://doi.org/10.1134/S0022476617030295
ID: 161345

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Abstract

A new dinuclear nitrido-bridged ruthenium complex with pyridine ligands ([PyH][Ru₂N(Py)₄Cl₆] (1) is synthesized by reacting K₃[Ru₂NCl₈(H₂O)2] (2) and excessive pyridine, then crystallized from dilute hydrochloric acid. Its crystal structure is determined by single crystal X-ray diffraction. The complex crystallizes in the form of red block crystals of the monoclinic symmetry and the space group C₂. The nitrido-bridged ruthenium complex has very short Ru–N distances.