Отправить статью по E-mail Induced currents and an 1H NMR chemical shifts in transition metal clusters (μ-H)2Fe3(μ3-Q)(CO)9 (Q = S, Se, Te)
- Авторы: Ryzhikov M.R.1,2, Kozlova S.G.1,2
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Учреждения:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Выпуск: Том 58, № 5 (2017)
- Страницы: 861-865
- Раздел: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/161475
- DOI: https://doi.org/10.1134/S002247661705002X
- ID: 161475
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Аннотация
The quantum chemical calculations of induced electric currents in (μ-H)2Fe3(μ3-Q)(CO)9 complexes, where Q = S, Se, Te, are carried out. It is demonstrated that the appearance of anomalous 1Н NMR chemical shifts on bridging hydrogen atoms is, first of all, due to the effect of induced currents on iron atoms.
Об авторах
M. Ryzhikov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: sgk@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
S. Kozlova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Автор, ответственный за переписку.
Email: sgk@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
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