A Complex Powder X-Ray Diffraction Study of Copper-Cerium Oxide Catalysts Prepared by the Pechini Method

Abstract

By means of a complex of powder X-ray diffraction techniques the features of the structural organization of highly dispersed copper-cerium CuO-CeO₂ catalysts prepared by the Pechini method are studied. The current structural technique for studying nanomaterials, namely the atomic pair (interatomic distances) distribution function analysis, is used to refine the phase composition of materials with revealing highly dispersed compounds, sizes of atomic ordering regions, and possible defects. It is shown that materials synthesized from polymeric precursors represent mixed CuO-CeO₂ oxides with a high concentration of structural defects. Highly dispersed individual copper compounds are not detected. The results obtained support the previous assumptions that copper cations can incorporate into the structure of cerium dioxide in the composition of copper-cerium catalysts.