Email this article Synthesis and Crystal Structure of Chloride complexes of Rh(III) Diammino- and Monoammino Series
- Authors: Baidina I.A.1, Belyaev A.V.1, Korolkov I.V.1,2, Smolentsev A.I.1, Vorobieva S.N.1
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Issue: Vol 60, No 9 (2019)
- Pages: 1482-1488
- Section: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/162190
- DOI: https://doi.org/10.1134/S0022476619090130
- ID: 162190
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Abstract
Complex compounds cis-K[Rh(NH3)2Cl4]·KCl (I), cis-K[Rh(NH3)2Cl3(NO2)] (II), and K2[Rh(NH3)Cl5] (III) are synthesized. The single crystal X-ray diffraction analysis of the compounds obtained is performed at T = 296 K. Crystallographic data for I are: a = 11.822(5) Å, b = 11.608(5) Å, c = 8.196(4) Å, β = 107.56(2)°, space group C2/m, Z = 4, dcalc = 2.431 g/cm3. For II: a = 8.946(3) Å, b = 5.941(2) Å, c = 8.182(3) Å, space group Pmn21, Z = 2, dcalc= 2.509 g/cm3. For III: a = 13.464(6) Å, b = 9.989(4) Å, c = 6.932(3) Å, space group Pnma, Z = 4, dcalc = 2.675 g/cm3. The compounds are characterized by IR spectroscopy, powder X-ray diffraction, and chemical analysis.
About the authors
I. A. Baidina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: baidina@niic.nsc.ru
Russian Federation, Novosibirsk
A. V. Belyaev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: baidina@niic.nsc.ru
Russian Federation, Novosibirsk
I. V. Korolkov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: baidina@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
A. I. Smolentsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: baidina@niic.nsc.ru
Russian Federation, Novosibirsk
S. N. Vorobieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: baidina@niic.nsc.ru
Russian Federation, Novosibirsk
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