An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine
- Авторы: Ivanova T.M.1, Sidorov A.A.1, Mazalov L.N.2,3, Fedorenko A.D.2, Kiskin M.A.1, Savilov S.V.1,4, Lunin V.V.1,4, Novotortsev V.M.1, Eremenko I.L.1, Kalinkin A.V.5, Fedoseeva Y.V.2, Okotrub A.V.2,3
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Учреждения:
- Kurnakov Institute of General and Inorganic Chemistry
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Moscow State University
- Boreskov Institute of Catalysis, Siberian Branch
- Выпуск: Том 60, № 6 (2019)
- Страницы: 909-918
- Раздел: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/162129
- DOI: https://doi.org/10.1134/S0022476619060052
- ID: 162129
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Аннотация
The electronic structure of mono- and binuclear platinum complexes with N-phenyl-o benzosemiquinondiimine ligands was studied using X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, and the density functional theory. The oxidation state of the central platinum ion corresponds to that of Pt(II). Upon the transition from the trans-complex 1 to the cis-complex 2 and to the binuclear complex 3, the electron density on platinum and nitrogen atoms decreases thus testifying the participation of platinum and nitrogen atoms in the oxidation processes and in the formation of binuclear complex 3.
Об авторах
T. Ivanova
Kurnakov Institute of General and Inorganic Chemistry
Email: fedorenko@niic.nsc.ru
Россия, Moscow
A. Sidorov
Kurnakov Institute of General and Inorganic Chemistry
Email: fedorenko@niic.nsc.ru
Россия, Moscow
L. Mazalov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: fedorenko@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
A. Fedorenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Автор, ответственный за переписку.
Email: fedorenko@niic.nsc.ru
Россия, Novosibirsk
M. Kiskin
Kurnakov Institute of General and Inorganic Chemistry
Email: fedorenko@niic.nsc.ru
Россия, Moscow
S. Savilov
Kurnakov Institute of General and Inorganic Chemistry; Moscow State University
Email: fedorenko@niic.nsc.ru
Россия, Moscow; Moscow
V. Lunin
Kurnakov Institute of General and Inorganic Chemistry; Moscow State University
Email: fedorenko@niic.nsc.ru
Россия, Moscow; Moscow
V. Novotortsev
Kurnakov Institute of General and Inorganic Chemistry
Email: fedorenko@niic.nsc.ru
Россия, Moscow
I. Eremenko
Kurnakov Institute of General and Inorganic Chemistry
Email: fedorenko@niic.nsc.ru
Россия, Moscow
A. Kalinkin
Boreskov Institute of Catalysis, Siberian Branch
Email: fedorenko@niic.nsc.ru
Россия, Novosibirsk
Yu. Fedoseeva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: fedorenko@niic.nsc.ru
Россия, Novosibirsk
A. Okotrub
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: fedorenko@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
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