Electronic and Crystal Structures of Nitrogen-Containing Electroconductive and Electroactive Polymers


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Abstract

Current ideas about the electronic and crystal structures of nitrogen-containing conductive polymers are considered. A comparative critical analysis of literature data on electronic, vibrational, and NMR spectra for different nuclei, and X-ray diffraction data for various forms of polyaniline, polyphenylenediamine, and polypyrrole is presented. Particular attention is paid to the relationship between the electronic and crystal structure of nitrogen-containing polyconjugated systems and their electrical conductivity.

About the authors

Ya. O. Mezhuev

Mendeleev University of Chemical Technology of Russia

Author for correspondence.
Email: valsorja@mail.ru
Russian Federation, Moscow

Yu. V. Korshak

Mendeleev University of Chemical Technology of Russia

Email: valsorja@mail.ru
Russian Federation, Moscow

M. I. Shtilman

Mendeleev University of Chemical Technology of Russia

Email: valsorja@mail.ru
Russian Federation, Moscow

S. E. Pokhil

Mendeleev University of Chemical Technology of Russia

Email: valsorja@mail.ru
Russian Federation, Moscow

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