Inclusion Compound of Phthalic Anhydride in Porous Homochiral Zinc Terephthalate Lactate: The Effect of Guests on the Geometrical Characteristics of the Metal-Organic Framework

M. S. Zavakhina; I. S. Khan; D. G. Samsonenko; V. P. Fedin

doi:10.1134/S0022476619020148

Inclusion Compound of Phthalic Anhydride in Porous Homochiral Zinc Terephthalate Lactate: The Effect of Guests on the Geometrical Characteristics of the Metal-Organic Framework

Authors: Zavakhina M.S.¹^,2, Khan I.S.¹, Samsonenko D.G.¹^,2, Fedin V.P.¹^,2
Affiliations:
1. Nikolaev Institute of Inorganic Chemistry
2. Novosibirsk State University
Issue: Vol 60, No 2 (2019)
Pages: 284-288
Section: Article
URL: https://journals.rcsi.science/0022-4766/article/view/162057
DOI: https://doi.org/10.1134/S0022476619020148
ID: 162057

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Abstract

The inclusion compound [Zn₂(dmf)(bdc)(S-lac)] · 0.5FTA (FTA = phthalic anhydride) is obtained by keeping the crystals of porous homochiral metal-organic coordination polymer [Zn₂(dmf)(bdc)(S-lac)] · DMF (DMF = N,N-dimethylformamide, H₂bdc = terephthalic acid, S-H₂lac = S-lactic acid) with excess phthalic anhydride at 100 °C. The crystal structure of the compound is determined by X-ray crystallography.