Ionic Mobility in 94BiF3-6KF and 84BiF3-6KF-10NdF3 Solid Solutions with Tysonite Structure


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Abstract

Ionic mobility in solid solutions with tysonite structure obtained by doping bismuth trifluoride with potassium and neodymium fluorides is studied using 19F NMR. The types of ionic motions are determined in the fluoride sublattice of the synthesized solid solutions at 150–450 K, their activation energies are estimated.

About the authors

V. Ya. Kavun

Institute of Chemistry, Far East Branch

Author for correspondence.
Email: kavun@ich.dvo.ru
Russian Federation, Vladivostok

M. M. Polyantsev

Institute of Chemistry, Far East Branch

Email: kavun@ich.dvo.ru
Russian Federation, Vladivostok

E. B. Merkulov

Institute of Chemistry, Far East Branch

Email: kavun@ich.dvo.ru
Russian Federation, Vladivostok

V. K. Goncharuk

Institute of Chemistry, Far East Branch

Email: kavun@ich.dvo.ru
Russian Federation, Vladivostok

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