Structure of the Oxonium Compound of Pefloxacinium Hexachloridostannate(IV)
- Authors: Vasiliev A.D.1,2, Golovnev N.N.1
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Affiliations:
- Siberian Federal University
- Kirensky Institute of Physics, Federal Research Center KSC, Siberian Branch
- Issue: Vol 59, No 3 (2018)
- Pages: 641-645
- Section: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/161920
- DOI: https://doi.org/10.1134/S0022476618030198
- ID: 161920
Cite item
Abstract
The structure of tris{hexachloridostannate(IV)}-hexachloride-tetrakis(pefloxacinium)-tetraoxonium undecahydrate (CCDC 1551760) 4PefH32+, 4H3O+, 3SnCl62−, 6Cl−, 11H2O (I), (PefH is pefloxacin) is determined. The I crystals are triclinic: a = 13.5474(10) Å, b = 15.2859(11) Å, c = 15.6586(11) Å, α = 94.467(1)°, β = 105.477(1)°, γ = 111.560(1)°, V = 2849.9(4) Å3, space group Pī, Z = 1. The structure is stabilized by multiple intermolecular hydrogen bonds and π–π-interactions between the PefH32+ ions.
About the authors
A. D. Vasiliev
Siberian Federal University; Kirensky Institute of Physics, Federal Research Center KSC, Siberian Branch
Email: ngolovnev@sfu-kras.ru
Russian Federation, Krasnoyarsk; Krasnoyarsk
N. N. Golovnev
Siberian Federal University
Author for correspondence.
Email: ngolovnev@sfu-kras.ru
Russian Federation, Krasnoyarsk
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