Email this article Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]
- Authors: Cheplakova A.M.1,2, Fedoseev I.S.2, Dorovatovskii P.V.3, Lazarenko V.A.3, Zubavichus Y.V.3, Khrustalev V.N.4, Fedin V.P.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- National Research Center “Kurchatov Institute”
- Peoples’ Friendship University of Russia
- Issue: Vol 59, No 2 (2018)
- Pages: 494-496
- Section: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/161899
- DOI: https://doi.org/10.1134/S0022476618020348
- ID: 161899
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Abstract
The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ2-bridging ligand. The polymer chains are linked together by π–π interactions between the phenyl rings.
About the authors
A. M. Cheplakova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
I. S. Fedoseev
Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk
P. V. Dorovatovskii
National Research Center “Kurchatov Institute”
Email: cluster@niic.nsc.ru
Russian Federation, Moscow
V. A. Lazarenko
National Research Center “Kurchatov Institute”
Email: cluster@niic.nsc.ru
Russian Federation, Moscow
Ya. V. Zubavichus
National Research Center “Kurchatov Institute”
Email: cluster@niic.nsc.ru
Russian Federation, Moscow
V. N. Khrustalev
Peoples’ Friendship University of Russia
Email: cluster@niic.nsc.ru
Russian Federation, Moscow
V. P. Fedin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Author for correspondence.
Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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