Email this article Structure Of Chain Coordination Polymer {[Nd(phen)2(H2O)Nd(phen)(H2O)3(μ-OH)2]· ·[Re4S4(CN)12]}·phen·3.5H2O
- Authors: Litvinova Y.M.1, Kuratieva N.V.1,2, Gayfulin Y.M.1, Mironov Y.V.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Issue: Vol 59, No 2 (2018)
- Pages: 429-432
- Section: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/161890
- DOI: https://doi.org/10.1134/S0022476618020257
- ID: 161890
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Abstract
A novel chain polymer based on cluster [Re4S4(CN)12]4– anion and Nd3+ cations is obtained by the hydrothermal synthesis. The structure of compound {[Nd(phen)2(H2O)Nd(phen)(H2O)3(μ-OH)2][Re4S4(CN)12]}·0.5phen·3.5H2O (1) is determined by single crystal X-ray diffraction. The compound crystallizes in the space group Pī with the cell parameters a = 12.8818(5) Å, b = 14.1219(5) Å, c = 22.0347(9) Å, α = 98.168(2)°, β = 93.518(2)°, γ = 95.734(2)°, V = 3936.3(3) Å3.
About the authors
Yu. M. Litvinova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: litvjm@gmail.com
Russian Federation, Novosibirsk
N. V. Kuratieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: litvjm@gmail.com
Russian Federation, Novosibirsk; Novosibirsk
Ya. M. Gayfulin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: litvjm@gmail.com
Russian Federation, Novosibirsk
Yu. V. Mironov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: litvjm@gmail.com
Russian Federation, Novosibirsk; Novosibirsk
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