Отправить статью по E-mail New Co(II) And Mn(II) Complexes with 4′-Substituted 2,2′:6′,2″-Terpyridine Ligands
- Авторы: Fu W.1, Shu X.1, Luo Y.1, Tang Z.1, Li Q.1, Liu H.1, Cheng Q.1, Wang H.1, Liu Y.1
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Учреждения:
- Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province, College of Chemistry and Materials Science
- Выпуск: Том 59, № 2 (2018)
- Страницы: 398-410
- Раздел: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/161886
- DOI: https://doi.org/10.1134/S002247661802021X
- ID: 161886
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Аннотация
Three Co(II) complexes [Co(meophtpy)2](ClO4)2·2CH3CN (1), [Co(nh2phtpy)2](ClO4)2·2CH3CN (2), [Co(ftpy)2](ClO4)2·2CH3CN (3) and three Mn(II) complexes [Mn(nme2phtpy)2]·(ClO4)2·2CH3CN (4), [Mn(ftpy)2](ClO4)2·CH3CN (5), [Mn(meophtpy)(H2O)(NO3)2]·CH3CN (6) (meophtpy, 4′-(4- methoxyphenyl)-2,2′:6′,2″-terpyridine; nh2phtpy, 4′-(4-aminophenyl)-2,2′:6′,2″-terpyridine; ftpy, 4′-(furan- 2-yl)-2,2′:6′,2″-terpyridine; nme2phtpy, 4′-(4-(N,N-dimethylamino)phenyl)-2,2′:6′,2″-terpyridine) are synthesized and their structures are determined by single crystal X-ray diffraction. Crystal data for 1 are: monoclinic, space group C2/c, a = 14.4781(5) Å, b = 16.2221(7) Å, c = 21.3617(9) Å, and Z = 4. For 2: monoclinic, space group C2/c, a = 14.554(6) Å, b = 15.239(6) Å, c = 21.754(9) Å, and Z = 4. For 3: monoclinic, space group C2/c, a = 14.5285(16) Å, b = 15.3234(16) Å, c = 21.154(2) Å, and Z = 4. For 4: triclinic, space group P-1, a = 12.132(5) Å, b = 12.536(5) Å, c =17.840(10) Å, and Z = 2. For 5: triclinic, space group P-1, a = 9.993(10) Å, b = 13.950(13) Å, c = 15.511(15) Å, and Z = 2. For 6: monoclinic, space group Pc, a = 12.402(7) Å, b = 12.919(8) Å, c = 7.893(5) Å, and Z = 2. In complexes 1–5, Co(II) or Mn(II) ions are coordinated by six N atoms from two terpyridine moieties. In complex 6 the Mn(II) atom coordinates only one terpyridine ligand. All these complexes are linked by hydrogen bonds and face-to-face π–π interactions into three-dimensional networks. In complexes 4–6 the available solvent areas imply their potential applications in gas adsorption or catalysis.
Об авторах
W.-W. Fu
Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province, College of Chemistry and Materials Science
Автор, ответственный за переписку.
Email: w.w.fu@hynu.edu.cn
Китай, Hengyang
X. Shu
Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province, College of Chemistry and Materials Science
Email: w.w.fu@hynu.edu.cn
Китай, Hengyang
Y.-L. Luo
Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province, College of Chemistry and Materials Science
Email: w.w.fu@hynu.edu.cn
Китай, Hengyang
Z.-Q. Tang
Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province, College of Chemistry and Materials Science
Email: w.w.fu@hynu.edu.cn
Китай, Hengyang
Q. Li
Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province, College of Chemistry and Materials Science
Email: w.w.fu@hynu.edu.cn
Китай, Hengyang
H.-J. Liu
Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province, College of Chemistry and Materials Science
Email: w.w.fu@hynu.edu.cn
Китай, Hengyang
Q.-W. Cheng
Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province, College of Chemistry and Materials Science
Email: w.w.fu@hynu.edu.cn
Китай, Hengyang
H.-Y. Wang
Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province, College of Chemistry and Materials Science
Email: w.w.fu@hynu.edu.cn
Китай, Hengyang
Y. Liu
Key Laboratory of Functional Organometallic Materials of General Colleges and Universities in Hunan Province, College of Chemistry and Materials Science
Email: w.w.fu@hynu.edu.cn
Китай, Hengyang
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