Synthesis, Crystal Structure and Fluorescent Property of a Onedimensional Coordination Polymer Constructed By 1,3-Bis(1,2,4-Triazol-1-Ylmethyl)- Benzene And 4,4′-Oxydiphthalic Acid
- Авторы: Yuan C.1, Liu S.N.1, Xu X.J.1
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Учреждения:
- School of Chemistry and Chemical Engineering
- Выпуск: Том 59, № 8 (2018)
- Страницы: 1928-1934
- Раздел: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/161813
- DOI: https://doi.org/10.1134/S0022476618080231
- ID: 161813
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Аннотация
A one-dimensional Cd(II) complex [Cd(H3ODPT)2(MBTZ)2.2H2O]n (1) (MBTZ = 1,3-bis(1,2,4-triazol-1- yl-methyl)benzene, H4ODPT = 4,4′-oxydiphthalic acid) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. Single crystal X-ray diffraction analysis reveals that complex 1 is a one-dimensional double chain polymer containing 24-membered rings with MBTZ ligands as the bridges arranged parallel to the b crystal direction, while the singly deprotonated H4ODPT ligands are extended on both sides of such double chains. In addition, the luminescence measurements reveal that complex 1 exhibits strong fluorescent emission in the solid state at room temperature.
Об авторах
C. Yuan
School of Chemistry and Chemical Engineering
Email: xxjyctu@gmail.com
Китай, Jiangsu
S. Liu
School of Chemistry and Chemical Engineering
Email: xxjyctu@gmail.com
Китай, Jiangsu
X. Xu
School of Chemistry and Chemical Engineering
Автор, ответственный за переписку.
Email: xxjyctu@gmail.com
Китай, Jiangsu
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