Crystal structure of the copper(II) complex with acetylacetone and ethylenediamine obtained by template synthesis

A. M. Maharramov; M. G. Tsintsadze; R. A. Alieva; F. N. Bahmanova; F. O. Mamedova; R. K. Askerov; F. S. Alieva; F. M. Chyragov

doi:10.1134/S0022476617040291

Crystal structure of the copper(II) complex with acetylacetone and ethylenediamine obtained by template synthesis

Authors: Maharramov A.M.¹, Tsintsadze M.G.², Alieva R.A.¹, Bahmanova F.N.¹, Mamedova F.O.³, Askerov R.K.¹, Alieva F.S.¹, Chyragov F.M.¹
Affiliations:
1. Baku State University
2. Georgian Technical University
3. Gandzha State University
Issue: Vol 58, No 4 (2017)
Pages: 828-830
Section: Brief Communications
URL: https://journals.rcsi.science/0022-4766/article/view/161454
DOI: https://doi.org/10.1134/S0022476617040291
ID: 161454

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Abstract

A new copper(II) complex with acetylacetone and ethylenediamine is obtained using the template synthesis. It is studied by single crystal X-ray diffraction. The crystals are monoclinic: а = 7.7563(4) Å, b = 24.0157(12) Å, c = 24.6353(13) Å, β = 91.9490(10)°, V = 4586.2(4) Å³, space group P2(1)/c, Z = 2, d_calc = 1.713 g/cm³, R = 0.0695. The copper atom environment consists of two oxygen and two nitrogen atoms of the ligand, forming a slightly distorted square.