Email this article Hexanuclear Na(I) complex with 3,5-dimethyl-1H-pyrazole and its anion
- Authors: Vinogradova K.A.1, Stabnikov P.A.1, Alferova N.I.1, Naumov D.Y.1, Rumyantsev Y.M.1
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Issue: Vol 58, No 4 (2017)
- Pages: 824-827
- Section: Brief Communications
- URL: https://journals.rcsi.science/0022-4766/article/view/161453
- DOI: https://doi.org/10.1134/S002247661704028X
- ID: 161453
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Abstract
The crystal structure of a hexanuclear Na(I) complex based on 3,5-dimethyl-1H-pyrazole (C5H8N2) and its anion is determined (space group P21/c, a = 12.2194(5) Å, b = 24.1554(9) Å, c = 11.3311(4) Å, β = 109.942(1)°, V = 3143.99(8) Å3, Z = 2). The crystal structure is formed by Na6(C5H8N2)4(C5H7N2)6 molecules. Thermogravimetric studies show that the compound exhibits volatility at elevated temperatures. The compound can be used in chemical gas-phase deposition processes.
About the authors
K. A. Vinogradova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: vinogradova@niic.nsc.ru
Russian Federation, Novosibirsk
P. A. Stabnikov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: vinogradova@niic.nsc.ru
Russian Federation, Novosibirsk
N. I. Alferova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: vinogradova@niic.nsc.ru
Russian Federation, Novosibirsk
D. Yu. Naumov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: vinogradova@niic.nsc.ru
Russian Federation, Novosibirsk
Yu. M. Rumyantsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: vinogradova@niic.nsc.ru
Russian Federation, Novosibirsk
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