Crystal structure of new ammonium fluoroindate(III) (NH4)2[InF5]
- 作者: Davidovich R.L.1, Logvinova V.B.1, Tkachev V.V.2, Shilov G.V.2
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隶属关系:
- Institute of Chemistry, Far Eastern Branch
- Institute of Problems of Chemical Physics
- 期: 卷 58, 编号 3 (2017)
- 页面: 585-587
- 栏目: Brief Communications
- URL: https://journals.rcsi.science/0022-4766/article/view/161310
- DOI: https://doi.org/10.1134/S0022476617030192
- ID: 161310
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详细
A new indium(III) fluoride complex with the ammonium cation (NH4)2[InF5] is synthesized and its crystal structure is studied. The structure of (NH4)2[InF5] is formed of NH4+ cations and complex [InF5]2– anions. The In atom in the complex anion surrounded by four terminal and two bridging F atoms forms an almost regular octahedral coordination polyhedron (CN 6) with two terminal F atoms in the axial positions and two terminal and two bridging F atoms in the equatorial plane. Through bridging F atoms, the InF6 polyhedra are arranged in polymer trans- vertex-connected corrugated anion chains (InF5)n2n− directed along the c axis. The N–H⋯F hydrogen bonds organize the chains in a three-dimensional framework.
作者简介
R. Davidovich
Institute of Chemistry, Far Eastern Branch
编辑信件的主要联系方式.
Email: davidovich@ich.dvo.ru
俄罗斯联邦, Vladivostok
V. Logvinova
Institute of Chemistry, Far Eastern Branch
Email: davidovich@ich.dvo.ru
俄罗斯联邦, Vladivostok
V. Tkachev
Institute of Problems of Chemical Physics
Email: davidovich@ich.dvo.ru
俄罗斯联邦, Chernogolovka
G. Shilov
Institute of Problems of Chemical Physics
Email: davidovich@ich.dvo.ru
俄罗斯联邦, Chernogolovka
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