Crystal structure of new ammonium fluoroindate(III) (NH4)2[InF5]


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A new indium(III) fluoride complex with the ammonium cation (NH4)2[InF5] is synthesized and its crystal structure is studied. The structure of (NH4)2[InF5] is formed of NH4+ cations and complex [InF5]2– anions. The In atom in the complex anion surrounded by four terminal and two bridging F atoms forms an almost regular octahedral coordination polyhedron (CN 6) with two terminal F atoms in the axial positions and two terminal and two bridging F atoms in the equatorial plane. Through bridging F atoms, the InF6 polyhedra are arranged in polymer trans- vertex-connected corrugated anion chains (InF5)n2n directed along the c axis. The N–H⋯F hydrogen bonds organize the chains in a three-dimensional framework.

作者简介

R. Davidovich

Institute of Chemistry, Far Eastern Branch

编辑信件的主要联系方式.
Email: davidovich@ich.dvo.ru
俄罗斯联邦, Vladivostok

V. Logvinova

Institute of Chemistry, Far Eastern Branch

Email: davidovich@ich.dvo.ru
俄罗斯联邦, Vladivostok

V. Tkachev

Institute of Problems of Chemical Physics

Email: davidovich@ich.dvo.ru
俄罗斯联邦, Chernogolovka

G. Shilov

Institute of Problems of Chemical Physics

Email: davidovich@ich.dvo.ru
俄罗斯联邦, Chernogolovka

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