Enviar artigo por via de e-mail Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]
- Autores: Gayfulin Y.M.1, Smolentsev A.I.1,2, Mironov Y.V.1,2, Naumov N.G.1,2
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Afiliações:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Edição: Volume 58, Nº 1 (2017)
- Páginas: 203-206
- Seção: Brief Communications
- URL: https://journals.rcsi.science/0022-4766/article/view/161124
- DOI: https://doi.org/10.1134/S0022476617010292
- ID: 161124
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Resumo
Rhenium-molybdenum cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] (1) and K4.4Cs1.6[Re3Mo3S8(CN)5] (2) are obtained by the interaction of an equimolar mixture of ReS2 and MoS2 with molten KCN and RbI/CsCl, respectively. The structure of the complexes is determined by the XRD method. The compounds crystallize in the tetragonal crystal system, space group I4/m. The crystal structure is composed of anionic chains of [Re3Mo3S8(CN)4(CN)2/2]6– aligned along the a crystallographic axis and M+ cations located in voids of the lattice. The effect of additional Cs+ and Rb+ cations on the crystallographic parameters and geometric characteristics of the clusters is analyzed.
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Sobre autores
Ya. Gayfulin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Autor responsável pela correspondência
Email: gayfulin@niic.nsc.ru
Rússia, Novosibirsk
A. Smolentsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: gayfulin@niic.nsc.ru
Rússia, Novosibirsk; Novosibirsk
Yu. Mironov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: gayfulin@niic.nsc.ru
Rússia, Novosibirsk; Novosibirsk
N. Naumov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: gayfulin@niic.nsc.ru
Rússia, Novosibirsk; Novosibirsk
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