Investigation of adamantane–diamond transformation. The radical mechanism of the formation of diamond nanoparticles under shock-wave action on adamantane
- Авторы: Tolochko B.P.1,2, Chernyshev A.P.1, Bokhonov B.B.1, Ten K.A.3, Pruuel E.R.3, Lyakhov N.Z.1
- 
							Учреждения: 
							- Institue of Solid State Chemistry and Mechanochemistry Siberian Branch
- Budker Institute of Nuclear Physics, Siberian Branch
- Lavrentyev Institute of Hydrodynamics, Siberian Branch
 
- Выпуск: Том 57, № 7 (2016)
- Страницы: 1469-1476
- Раздел: Applications of Synchrotron Radiation in Structural Chemistry
- URL: https://journals.rcsi.science/0022-4766/article/view/160704
- DOI: https://doi.org/10.1134/S0022476616070234
- ID: 160704
Цитировать
Аннотация
The use of the modern installations with the synchrotron radiation allowed obtaining the information about the dynamics of rapid transformation of adamantane into diamond within 2 μs under shock-wave action with nanosecond time resolution. The yield of diamond was 30%. An explanation of adamantane-diamond transformation is proposed. Hydrogen evolved during adamantane decomposition easily diffuses over diamond lattice. However, during synthesis time (~1 μs) hydrogen does not have enough time to go out of diamond particles. Experiment was made at accelerate complex VEPP-3/VEPP-4.
Об авторах
B. Tolochko
Institue of Solid State Chemistry and Mechanochemistry Siberian Branch; Budker Institute of Nuclear Physics, Siberian Branch
							Автор, ответственный за переписку.
							Email: B.P.Tolochko@inp.nsk.su
				                					                																			                												                	Россия, 							Novosibirsk; Novosibirsk						
A. Chernyshev
Institue of Solid State Chemistry and Mechanochemistry Siberian Branch
														Email: B.P.Tolochko@inp.nsk.su
				                					                																			                												                	Россия, 							Novosibirsk						
B. Bokhonov
Institue of Solid State Chemistry and Mechanochemistry Siberian Branch
														Email: B.P.Tolochko@inp.nsk.su
				                					                																			                												                	Россия, 							Novosibirsk						
K. Ten
Lavrentyev Institute of Hydrodynamics, Siberian Branch
														Email: B.P.Tolochko@inp.nsk.su
				                					                																			                												                	Россия, 							Novosibirsk						
E. Pruuel
Lavrentyev Institute of Hydrodynamics, Siberian Branch
														Email: B.P.Tolochko@inp.nsk.su
				                					                																			                												                	Россия, 							Novosibirsk						
N. Lyakhov
Institue of Solid State Chemistry and Mechanochemistry Siberian Branch
														Email: B.P.Tolochko@inp.nsk.su
				                					                																			                												                	Россия, 							Novosibirsk						
Дополнительные файлы
 
				
			 
						 
					 
						 
						 
						 
									 
  
  
  
  
  Отправить статью по E-mail
			Отправить статью по E-mail  Открытый доступ
		                                Открытый доступ Доступ предоставлен
						Доступ предоставлен Только для подписчиков
		                                		                                        Только для подписчиков
		                                					