Email this article New data on the structure of α-trans-[Pd(NH3)2Cl2]
- Authors: Naumov D.Y.1, Khranenko S.P.1, Kuratieva N.V.1,2, Panchenko A.V.1,2, Gromilov S.A.1,2
-
Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Issue: Vol 57, No 8 (2016)
- Pages: 1600-1605
- Section: Article
- URL: https://journals.rcsi.science/0022-4766/article/view/160428
- DOI: https://doi.org/10.1134/S0022476616080163
- ID: 160428
Cite item
Open Access
Access granted
Subscription Access
Abstract
Single crystal X-ray diffraction was applied for re-determination of the crystal structure of α-trans-[Pd(NH3)2Cl2]. It has been demonstrated that, in contrast to the literature data, the structure is disordered. This model does not require excess over-stoichiometric palladium. Two crystals obtained in the same experiment illustrate possible variations in the packing of the molecules of the complex.
About the authors
D. Yu. Naumov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: grom@niic.nsc.ru
Russian Federation, Novosibirsk
S. P. Khranenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: grom@niic.nsc.ru
Russian Federation, Novosibirsk
N. V. Kuratieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: grom@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
A. V. Panchenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: grom@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
S. A. Gromilov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Author for correspondence.
Email: grom@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
Supplementary files
