Отправить статью по E-mail Crystal structure of [Pb3(OH)4Co(NO2)3](NO3)(NO2)·2H2O
- Авторы: Khranenko S.P.1, Kuratieva N.V.1,2, Korolkov I.V.1,2, Gromilov S.A.1,2
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Учреждения:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Выпуск: Том 57, № 3 (2016)
- Страницы: 625-627
- Раздел: Brief Communications
- URL: https://journals.rcsi.science/0022-4766/article/view/159830
- DOI: https://doi.org/10.1134/S0022476616030240
- ID: 159830
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Аннотация
The structure of [Pb3(OH)4Co(NO2)3](NO3)(NO2)·2H2O is determined by single crystal X-ray diffraction. The crystallographic characteristics are as follows: a = 8.9414(4) Å, b = 14.5330(5) Å, c = 24.9383(9) Å, V = 3240.6(2) Å3, space group Pbca, Z = 8. The Co(III) atoms have a slightly distorted octahedral coordination formed by three nitrogen atoms belonging to nitro groups (Co–Nav is 1.91 Å) and three oxygen atoms belonging to hydroxyl groups (Co–Oav is 1.93 Å). The hydroxyl groups act as μ3-bridges between the metal atoms. The geometric characteristics are analyzed and the packing motif is determined.
Об авторах
S. Khranenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: grom@niic.nsc.ru
Россия, Novosibirsk
N. Kuratieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: grom@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
I. Korolkov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: grom@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
S. Gromilov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Автор, ответственный за переписку.
Email: grom@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
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