Proton Conductivity of Water in Mesoporous Materials


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Abstract

A model explaining a high proton conductivity of water in mesoporous materials has been proposed. The model is based on the theory of an intermediate phase of water with an ordered oxygen lattice and a destroyed proton lattice and involves various types of interaction of water molecules with an interface. The model is in fact based on an analogy of the interface and a liquid-like surface layer of ice. Possible methods for increasing the proton conductivity, experiments for testing the proposed model, and application of the results to the creation of efficient proton-exchange membranes have been discussed.

About the authors

M. I. Ryzhkin

Institute of Solid State Physics

Email: ryzhkin@issp.ac.ru
Russian Federation, Chernogolovka, Moscow region, 142432

I. A. Ryzhkin

Institute of Solid State Physics; Inenergy Company Group

Author for correspondence.
Email: ryzhkin@issp.ac.ru
Russian Federation, Chernogolovka, Moscow region, 142432; Moscow, 111524

A. M. Kashin

Inenergy Company Group

Email: ryzhkin@issp.ac.ru
Russian Federation, Moscow, 111524

E. A. Galitskaya

Institute of Solid State Physics

Email: ryzhkin@issp.ac.ru
Russian Federation, Chernogolovka, Moscow region, 142432

V. V. Sinitsyn

Institute of Solid State Physics

Email: ryzhkin@issp.ac.ru
Russian Federation, Chernogolovka, Moscow region, 142432

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