Extraction Separation of Rare Earth Elements of the Medium Group with Isomolar Mixtures of Aliquat®336–TBP and Cyanex®572–TBP from Nitric Solutions


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Abstract

The results of extraction separation of the medium group of rare earth elements in the composition of the concentrate of JSC SMF with isomolar mixtures of Aliquat®336–TBP and Cyanex®572–TBP from nitric solutions are discussed. The influence of acidity of an aqueous solution on separation factors of representative pairs of REE and on the value of the capacity of mixtures of extractants is studied. The possibility of extraction separation on the lines of Sm–Gd and Eu–Gd (Aliquat®336–TBP) and on the line of Eu–Sm (Cyanex®572–TBP) is shown.

About the authors

S. S. Shulin

Dmitry Mendeleev University of Chemical Technology of Russia

Author for correspondence.
Email: shulinsergei@yandex.ru
Russian Federation, Moscow, 125047

G. N. Galieva

LLC Laboratory of Innovation Technologies of the Group of Companies of Skygrad

Email: shulinsergei@yandex.ru
Russian Federation, Korolev, 141090

S. V. Chighevskaya

Dmitry Mendeleev University of Chemical Technology of Russia

Email: shulinsergei@yandex.ru
Russian Federation, Moscow, 125047

J. V. Pletuhina

Dmitry Mendeleev University of Chemical Technology of Russia

Email: shulinsergei@yandex.ru
Russian Federation, Moscow, 125047

N. S. Saveliev

Dmitry Mendeleev University of Chemical Technology of Russia

Email: shulinsergei@yandex.ru
Russian Federation, Moscow, 125047

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