Mechanisms of the formation of a surface phase with the matrix composition in a Ca2Nb2O7 single crystal
- 作者: Tomashpolsky Y.Y.1, Matyuk V.M.1, Sadovskaya N.V.1
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隶属关系:
- Karpov Institute of Physical Chemistry (Russian State Scientific Center)
- 期: 卷 52, 编号 8 (2016)
- 页面: 791-795
- 栏目: Article
- URL: https://journals.rcsi.science/0020-1685/article/view/157831
- DOI: https://doi.org/10.1134/S0020168516080173
- ID: 157831
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详细
We have studied the local composition and nanoscale surface morphology of a calcium niobate, Сa2Nb2O7, single crystal after thermally stimulated heterosegregation with the aim of identifying the mechanisms underlying the formation of a surface phase with the matrix composition. The identity of the compositions of the surface phase and matrix is accounted for in terms of a liquid-phase model for surface segregation, which includes diffusion, melting, and crystallization processes.
作者简介
Yu. Tomashpolsky
Karpov Institute of Physical Chemistry (Russian State Scientific Center)
编辑信件的主要联系方式.
Email: tomash@nifhi.ru
俄罗斯联邦, per. Obukha 3-1/12, str. 6, Moscow, 105064
V. Matyuk
Karpov Institute of Physical Chemistry (Russian State Scientific Center)
Email: tomash@nifhi.ru
俄罗斯联邦, per. Obukha 3-1/12, str. 6, Moscow, 105064
N. Sadovskaya
Karpov Institute of Physical Chemistry (Russian State Scientific Center)
Email: tomash@nifhi.ru
俄罗斯联邦, per. Obukha 3-1/12, str. 6, Moscow, 105064
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