Synthesis, structure, and magnetic properties of rare-earth-doped Ni0.75Zn0.25Fe2O4 nickel zinc ferrite

Resumo

We have developed processes for the synthesis of Ni_0.75Zn_0.25Fe_2–xLn_xO₄ ferrite solid solutions with the spinel structure and investigated the effect of the rare-earth elements Nd, Gd, Yb, and Lu on the chemical composition, extent, lattice parameters, and magnetic properties of the solid solutions. The results demonstrate that rare-earth solubility in the parent spinel reaches ≈2.5 at %, which leads to changes in the magnetic characteristics of the material, in particular in its saturation magnetization M_s, T_C, and coercive force H_c.