Highly Oxygen-Permeable NiV2O6–25 wt % V2O5 Molten-Oxide Membrane Material


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Abstract

A NiV2O6–25 wt % V2O5 molten-oxide material has been prepared and characterized, and its transport properties (electrical conductivity, oxygen ion transport number, and oxygen permeability) have been studied in the temperature range 680–700°C. The results demonstrate that the molten-oxide membrane material obtained possesses high selective oxygen permeability (KO2 = (2.5–5.6) × 10–10 mol/(cm s) in the range 680–740°C and \(\frac{{{j_{{O_2}}}}}{{{j_{{N_2}}}}}\) ~ 1500) and can be used in separators for the preparation of extrapure oxygen from air.

About the authors

I. V. Kulbakin

Baikov Institute of Metallurgy and Materials Science

Author for correspondence.
Email: ivkulbakin@mail.ru
Russian Federation, Leninskii pr. 49, Moscow, 119334

A. A. Solovieva

Baikov Institute of Metallurgy and Materials Science

Email: ivkulbakin@mail.ru
Russian Federation, Leninskii pr. 49, Moscow, 119334

S. V. Fedorov

Baikov Institute of Metallurgy and Materials Science

Email: ivkulbakin@mail.ru
Russian Federation, Leninskii pr. 49, Moscow, 119334

V. V. Artemov

Crystallography and Photonics Federal Research Center

Email: ivkulbakin@mail.ru
Russian Federation, Leninskii pr. 59, Moscow, 119333

V. V. Belousov

Baikov Institute of Metallurgy and Materials Science

Email: ivkulbakin@mail.ru
Russian Federation, Leninskii pr. 49, Moscow, 119334

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