Reduction of GeCl4 in the presence of a catalyst based on modified NiCl2
- Authors: Kadomtseva A.V.1,2, Ob”edkov A.M.3
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Affiliations:
- Nizhny Novgorod State Medical Academy
- Alekseev State Technical University
- Razuvaev Institute of Organometallic Chemistry
- Issue: Vol 53, No 12 (2017)
- Pages: 1312-1318
- Section: Article
- URL: https://journals.rcsi.science/0020-1685/article/view/158343
- DOI: https://doi.org/10.1134/S0020168517120056
- ID: 158343
Cite item
Abstract
A method has been proposed for the hydrogen reduction of GeCl4 in the presence of a catalyst based on modified NiCl2, which makes it possible to lower the process temperature and reduce the number of steps in germanium preparation. The kinetic characteristics of the catalytic hydrogen reduction of GeCl4 have been determined.
About the authors
A. V. Kadomtseva
Nizhny Novgorod State Medical Academy; Alekseev State Technical University
Author for correspondence.
Email: kadomtseva@nizhgma.ru
Russian Federation, pl. Minina i Pozharskogo 10/1, Nizhny Novgorod, 603005; ul. Minina 24, Nizhny Novgorod, 603950
A. M. Ob”edkov
Razuvaev Institute of Organometallic Chemistry
Email: kadomtseva@nizhgma.ru
Russian Federation, ul. Tropinina 49, Nizhny Novgorod, 603950
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