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Vol 55, No 1 (2017)

Plasma Investigations

Calculation of thermophysical properties of titanium and zinc plasmas

Apfelbaum E.M.

Abstract

Thermophysical properties such as electron transport coefficients, ion composition, pressure, and internal energy are calculated for the plasma of titanium and zinc with densities 10–20 times less than normal density and at temperatures of 10–60 kK. The relaxation-time approximation and the generalized chemical model are used for calculations. The results obtained are compared with the data of experiments and calculation results of other researchers. For titanium, a good agreement with available experimental data and results of calculations by other models, including the first-principles calculations, is obtained, whereas, for zinc, a discrepancy between results of theoretical models and data of measurements for electrical conductivity is observed, which does not yet have an explanation.

High Temperature. 2017;55(1):1-11
pages 1-11 views

Low-voltage beam discharge in light inert gases to solve problems of voltage stabilization

Mustafaev A.S., Grabovskiy A.Y.

Abstract

By means of the flat one-sided probe, the electron velocity distribution function is investigated along with plasma parameters distribution and electrokinetic characteristics in short (without positive column) low-voltage beam discharge in helium, neon, and argon. With the pressure increase, the discharge voltage obtains the value of the excitation potential of the metastable level of the filling gas, Um. The results of the probe measurements of the electron velocity distribution function make it possible to calculate the generation functions of the inelastic process and to make the conclusion that, at attaining the critical pressure, Pcr, when the processes of atom stepwise ionization begin to dominate over the direct ionization, the discharge burning voltage drops below the ionization potential, Uion. Based on the performed studies, a technique and a device are proposed to stabilize the voltage within the range of 9–50 V by filling the interelectrode gap with inert gases of different excitation and ionization potentials.

High Temperature. 2017;55(1):20-26
pages 20-26 views

Spin states of electrons in quantum dots upon heating. Simulation by the Feynman path integral method. Magnetic properties

Shevkunov S.V.

Abstract

Temperature dependences of spin states and spin paramagnetic susceptibility in ellipsoidal quantum dots (QDs) containing two or three electrons are numerically simulated using ab initio calculations based on the Feynman path integral method. Limits of the thermal stability of spin states are estimated. Upon cooling, the pairing of spins of an electron pair is most intense in spherical QDs; notably, prolate QDs hinder the pairing more strongly than the oblate ones. When the spherical shape of a QD is distorted, a characteristic peak in the temperature dependence of the electron-pair magnetic susceptibility shifts to lower temperatures. A spin of the system of three electrons may either increase or decrease upon cooling, depending on the QD shape. In the case of three electrons, strong spatial anisotropy of the electron-confining field causes a relative decrease in the energy of states with large spin values.

High Temperature. 2017;55(1):12-19
pages 12-19 views

Thermophysical Properties of Materials

Construction of a system of kinetic equations for a nonideal gas

Bishaev A.M., Rykov V.A.

Abstract

For molecules interacting among each other with the potential having both repulsive and attractive components, a system of kinetic equations is derived using the Bogolyubov method, which takes into account the effect of forming bound states by molecules. This system implies all conservation laws and their corollaries that are invariant under the Galilean transformation. With consideration of the relaxation problem for the given system of kinetic equations, the Н-theorem can be obtained. It is noted that the equation of state, which is derived in this case, coincides in form with the van der Waals equation of state.

High Temperature. 2017;55(1):27-39
pages 27-39 views

Investigation of α-phase and liquid uranium by the method of quantum molecular dynamics

Yanilkin A.V.

Abstract

The thermodynamic properties of α-phase and liquid uranium have been investigated by the method of quantum molecular dynamics. The isotherms and equilibrium properties (pressure, temperature, and internal energy) along isochores and isotherms have been calculated for densities of 16.5–41.1 g/cm3 and temperatures up to 60000 K. The dependence of the thermal pressure on temperature and internal energy is analyzed. The melting boundary of α-phase uranium is estimated. The shock adiabat is calculated for pressures up to 1.5 TPa based on the equation of state derived here. The results obtained are in good agreement with the published experimental data and the results of calculations according to different theoretical models.

High Temperature. 2017;55(1):40-46
pages 40-46 views

Detection of trace impurities by time-of-flight mass spectrometry with laser-induced evaporation

Belyaev G.E., Vasin A.A., Lisitsyn A.V., Frolov A.M., Sheindlin M.A.

Abstract

A method for the determination of trace impurities of tens of ppm in solid materials is proposed, based on laser-induced evaporation of the substance in a vacuum in the forced congruence mode with simultaneous analysis of the evaporation products using a time-of-flight mass spectrometer. The results of measurements of the relative composition of impurities in α-corundum obtained from aluminum hydroxide (AlOOH) powder by high-temperature annealing (1500 and 1800°C) are presented. The necessity of comparative analysis is caused by a substantial difference in the measurement results for impurities in the initial material obtained by conventional methods. The reported values of the relative composition of impurities are in a good agreement with the results of inductively coupled plasma mass spectrometry.

High Temperature. 2017;55(1):57-62
pages 57-62 views

Molecular dynamics calculation of properties of liquid gallium and tin under shock compression

Belashchenko D.K.

Abstract

The embedded atom model (EAM) potentials are proposed, enabling the description of liquid gallium and tin under conditions typical to shock compression. The potentials reported earlier to describe metals under pressures close to normal and the experimental data on shock compression are used. Series of models are constructed 2000 or 2048 atoms in size in a basic cube at compression ratios Z up to 0.5 of the initial volume under pressures up to 385 GPa and temperatures up to 32000 K. These potentials give a satisfactory description of liquid gallium and tin under shock compression. The thermodynamic properties of the metals at compression ratios up to 0.5 and temperatures up to 20000 K are calculated and given in tabular form. In the case of gallium, a small compression of models with normal density decreases the total energy at 300, 500, 15000, and 20000 K, and, for tin, this effect is observed only at 20000 K. The energy and pressure of the FCC metal models are markedly lower than those of noncrystalline models. The cold pressure for the states at temperatures between 0 and 298 K is evaluated. The EAM potential of tin leads to a lowering of the cold pressure of an FCC lattice with respect to the amorphous phase at Z < 0.75.

High Temperature. 2017;55(1):47-56
pages 47-56 views

Inelastic collisions of molecules within the SFO model

Tsyganov D.L.

Abstract

An inelastic collision of diatomic molecule AB with structureless particle M (VT energy exchange) is considered within the SFO/SFHO model. An approach for determining the energy efficiency of excitation of molecular vibrational levels, energy-loss matrix, and total energy loss in a head-on collision with molecules/atoms is proposed. Nitrogen molecules N2 are chosen as AB and M. An interaction in the AB–M system is described using the “improved” Lennard-Jones potential.

High Temperature. 2017;55(1):63-69
pages 63-69 views

Improvement of thermodynamic efficiency of the humid biofuel application in the distributed generation power suppliers

Batenin V.M., Ivanov P.P., Kovbasyuk V.I.

Abstract

The problems of the humid biofuel application in the distributed energy engineering facilities are considered. Use of drying (and thermal proceeding) in energy saving makes it possible to perform efficient biofuel gasification, compensating for, in many cases, the negative influence of the moisture on the efficiency of the energy facilities. The complicated functional connection between the drying and the gasification processes as well as of the gasification product purification are analyzed. The cold purification, taken as the basic technology, reduces the efficiency of the gasification versions with the temperature above the level of the liquid slag removal; yet, if the temperature is not higher than the ash softening beginning, then this influence is insufficient. When compared, the efficiency of the STIG steam-gas facility on the humid fuel tends to be just a little lower than the dry fuel and reaches 45–49%. The calculations show that, at the low gasification temperature, we should not remove all the fuel moisture if the humidity is below 40%. The oxygen blast application in the gasifier reduces the efficiency to some extent but oxygen is necessary to accumulate the highenergy synthetic gas, in particular, for the peak or the exterior application.

High Temperature. 2017;55(1):70-74
pages 70-74 views

Heat and Mass Transfer and Physical Gasdynamics

Approximate analytical solution of a 2D problem for a heat conducting emitting plate

Cherkasov S.G., Laptev I.V.

Abstract

A stationary problem of the thermal state of a 2D emitting plate adjacent to a coolant carrying pipe is considered. The expression for approximate determination of the size of the plate emitting a given amount of heat is obtained. The criteria of applicability of the obtained solution are considered.

High Temperature. 2017;55(1):75-78
pages 75-78 views

Numerical simulation of power-engineering complex with torrefaction reactor

Direktor L.B., Zaichenko V.M., Sinelshchikov V.A.

Abstract

The paper presents a mathematical model of power-engineering complex implementing a combined technology of production of power, heat, and solid biofuels, namely, torrefied pellets. Torrefaction of fuel pellets is carried out in a thermochemical reactor by heat from exhaust gases of a gas piston power plant. The results of testing the model by experimental data and the results of calculations of the main characteristics of torrefaction, the mass and energy flows are given. The analysis results of efficiency of the power plant with a build-on thermochemical reactor are reported.

High Temperature. 2017;55(1):124-130
pages 124-130 views

Dynamics of interphase surface of self-sustaining evaporation front in liquid with additives of nanosized particles

Zhukov V.E., Pavlenko A.N., Moiseev M.I., Kuznetsov D.V.

Abstract

The results of experimental research on dynamics of propagation of self-sustaining evaporation front in the conditions of large volume are presented. Investigations were carried out using Freon R21, and also in R21 with the addition of SiO2 nanoparticles. The experimental data on the propagation velocity and structure of evaporation fronts were obtained. The spectral analysis of interphase boundary oscillations of evaporation front was obtained. The characteristic frequencies and oscillation amplitudes of interphase boundary depending on the temperature difference are determined. It is shown that the addition of nanoparticles considerably influences the initiation temperature of evaporation front, front velocity and the character of the oscillations of interphase boundary. The analysis of the results obtained is carried out from the perspective of the development of hydrodynamic instabilities in Landau formulation.

High Temperature. 2017;55(1):79-86
pages 79-86 views

Gas-dispersed jet flow around a solid in a wide range of stagnation parameters

Molleson G.V., Stasenko A.L.

Abstract

Characteristic gas-thermodynamic parameters of interaction of mono- and polydisperse jets with solids under pressures p0 up to 2 MPa and at stagnation temperatures T0 = 288–1750 K are investigated. The dependence of the velocity of collision of particles with the flowed solid on their material, size, and initial mass fraction in a settling chamber is taken into account. The regions of absolutely inelastic (erosion) and elastic (with a rebound) interactions of particles with the solid is studied. The semiempirical coefficient providing agreement between the theoretical and experimental densities of the heat flow, brought by particles to the solid in the mode of erosion interaction, is found for the case of a hot jet.

High Temperature. 2017;55(1):87-94
pages 87-94 views

Interaction of the acoustic signal with motionless discretely layered medium containing a layer of bubbly liquid

Gubaidullin D.A., Nikiforov A.A.

Abstract

The dynamics of the pulse perturbation of the low-amplitude pressure in the motionless discretely layered medium containing a layer of liquid with polydisperse gas bubbles has been studied theoretically. Theoretical method basics of the calculation of the acoustic signal distortion during the diagnostics of multilayer samples containing a layer of bubbly liquid are presented. It is shown that specific dispersion and dissipative properties of the layer of bubbly liquid can affect considerably the dynamics of the acoustic signal in the multilayer medium as a function of the main frequency of the signal. The theoretical models of the dynamics of multiphase media can be verified using this method. It was established that it is possible to use this theory for the calculation of the acoustic signal distortion at its interaction with multilayer objects containing the layer of bubbly liquid.

High Temperature. 2017;55(1):95-100
pages 95-100 views

Optimal way for choosing parameters of spacecraft’s screen-vacuum heat insulation

Formalev V.F., Kolesnik S.A., Selin I.A., Kuznetsova E.L.

Abstract

The heat transfer in multiple plate sandwiches of spacecraft’s screen-vacuum heat insulation is simulated for determining the characteristics of heat shielding against long-term solar heat flux. To choose optimal characteristics of heat shielding, it is necessary to determine precisely the number of plates and their peculiarities. The new, absolutely stable method for solving numerically heat transfer problems is presented. We obtain results showing that the screen-vacuum insulation is characterized by low heating-up inertance that is unacceptable. To remove this effect, the inertial heat shielding is used on the internal surface of the heat shielding and its state is examined.

High Temperature. 2017;55(1):101-106
pages 101-106 views

Semianalytic method for heat transfer calculation in the liquid film under conditions of a constant heat flux on the wall

Aktershev S.P., Bartashevich M.V., Chinnov E.A.

Abstract

For calculating the heat transfer in the free-falling liquid film, a semianalytic method is offered in which the temperature field in the liquid is presented as a series of basis functions which satisfies boundary conditions. The proposed method is demonstrated by the example of the problem regarding the film heating under conditions of the constant heat flux on the wall taking into account the heat transfer on the interfacial surface. The analytical solution is derived for the thermal initial section, on which the liquid heating occurs in a thin layer near the wall. Calculations using the proposed method are well agreed with the numerical solution obtained by the finite-difference method and with experimental data.

High Temperature. 2017;55(1):107-113
pages 107-113 views

Measurement of thermal relaxation and temperature damping time in a solid

Kirsanov Y.A., Kirsanov A.Y., Yudakhin A.E.

Abstract

Differential equations of heat conductance of solid body are presented, a result of Fourier, Cattaneo–Vernotte, and two-phase delay hypotheses. The experimental set-up and automated measuring system is described for the study of transient thermal processes in solid. The solution of the boundary problem of the third kind is given with differential equations of heat conductance of parabolic and hyperbolic types. The results of experimental and theoretical study of transient thermal processes in the plate center are given in the sudden immersion into a hot environment. Based on the comparison of theoretical transient processes with recorded automated measuring system, the adequacy of hypotheses and corresponding differential equations of heat conductance are concluded with respect to short-term transient processes. Thermal relaxation and temperature damping constants for polymethyl methacrylate are measured.

High Temperature. 2017;55(1):114-119
pages 114-119 views

Thermohydrodynamic studies of vertical wells with hydraulic fracturing of a reservoir

Khairullin M.K., Gadil’shina V.R., Shamsiev M.N., Morozov P.E., Abdullin A.I., Badertdinova E.R.

Abstract

A mathematical model to describe thermohydrodynamic processes in the system “oil reservoir–hydraulic fracture” is developed. A method for determining filtration and thermophysical parameters of the reservoir and fracture is proposed. Curves of the change of the downhole temperature and pressure are used as initial information.

High Temperature. 2017;55(1):120-123
pages 120-123 views

Stability of thermoviscous fluid flow under high temperature gradients

Kulikov Y.M., Son E.E.

Abstract

In present study the influence of temperature-dependent viscosity, i.e. thermoviscosity on the pressure-driven flow in inhomogeneous temperature field has been recalled. Such viscous stratification impacts on the velocity profile asymmetry, significantly increases the entry length, and causes the velocity inflection point to appear. In certain cases, particularly under high temperature differences of channel walls, the thermoviscosity generates instability that in a view of high local Reynolds numbers can create turbulent zones.

High Temperature. 2017;55(1):131-138
pages 131-138 views

Short Communications

2D numerical simulation of volume discharge with liquid anode

Gaisin A.F.

Abstract

Results are presented for the numerical simulation of the volume discharge between pin metal cathode and electrolyte anode. 2D distributions of electric field potential and ion and electron concentrations in the cylindrical geometry discharge gap are calculated. The peculiarities of the concentration distributions of the charged particles between metal cathode and liquid anode are revealed.

High Temperature. 2017;55(1):145-146
pages 145-146 views

On the possibility of generating nonstationary fire whirls under the conditions of solid fuel axisymmetric burning

Varaksin A.Y., Romash M.E., Kopeitsev V.N.

Abstract

It is demonstrated that free concentrated fire whirls can be physically modeled if the outer circulation is absent. Vortex structures were generated when hexamethylenetetramine pellets, located axially on a substrate (aluminum sheet) burned. The first data on specific features of fire whirl formation and some integral parameters (the lifetime, height, and diameter) were obtained using video shooting.

High Temperature. 2017;55(1):154-157
pages 154-157 views

Experimental study of the Er308LSI steel acoustic properties

Roshchupkin V.V., Lyakhovitskii M.M., Pokrasin M.A., Minina N.A.

Abstract

The experimental results on the acoustic properties (the ultrasound velocity and attenuation coefficient) and the relative thermal expansion of the Er308LSI steel within the temperature range of 20–1100°C are presented. Application of the dilatometer studies makes it possible to improve the accuracy of the experimental data on the acoustic properties and to calculate the temperature dependency of the steel density as well as of the Young modulus. The temperature dependencies and calculate the approximating equations for the investigated and the calculated properties of the steel are plotted.

High Temperature. 2017;55(1):147-149
pages 147-149 views

Thermophysical properties and thermodynamic functions of the beryllium, magnesium, and praseodymium alloyed Zn–55Al alloy

Obidov Z.R.

Abstract

The dependence of beryllium, magnesium, and praseodymium additives on the temperature dependences of the Zn–55Al alloy thermophysical properties and thermodynamic functions is investigated. With the increase in the alloying additive, the values of the studied properties increase with the temperature increase whereas the Gibbs energies decrease.

High Temperature. 2017;55(1):150-153
pages 150-153 views

On the relationship between microcanonical and canonical Gibbs distributions

Bobrov V.B., Trigger S.A., Petrov O.F.

Abstract

It is established that the agreement between the use of microcanonical and canonical Gibbs distributions is possible only if the temperature of a closed equilibrium system and its specific energy in a thermostat are mutually inverse functions. The analysis shows that the derivation of the canonical Gibbs distribution from the microcanoncial does not agree with the physical condition for separating a macroscopic part of a closed equilibrium system.

High Temperature. 2017;55(1):158-161
pages 158-161 views

Impact on blockage of an airflow containing solid particles

Kotelnikov A.L., Bazhenova T.V., Bivol G.Y., Lenkevich D.A.

Abstract

Experimental results are presented for the impact on blockage by airflow exhausted from a highpressure vessel and containing micron-sized solid particles. The static and the dynamic pressures on the blockage at different initial jet parameters are determined. The degree of the pressure increase on the blockage depending on the initial pressure in the vessel and the solid phase concentration is determined. The pressure of the flow with the powder on the blockage may be up to three times as much as the same in pure gas.

High Temperature. 2017;55(1):162-164
pages 162-164 views

High Temperature Apparatuses and Structures

Investigation on corrosion failure of Cr–Mo P11 grade pipe in primary section of a superheated steam generation system

Sabouri M., Faridi H.R.

Abstract

This paper presents failure analysis of corroded steam pipes (Cr–Mo, P11 grade) at ammonia production plant. The corrosion and deposition morphologies are characterized using scanning electron microscopy. In addition, elemental composition analysis of deposited corrosion products is carried out using energy dispersive X-ray. This study clearly indicates the sensitivity of P11 grade steel pipe to intensive oxygen corrosion in steam generation systems with improper implementation of deoxygenating processes. Furthermore, this pipe grade and oxide layer on its surface are susceptible to cracking at the presence of high-level thermal stresses.

High Temperature. 2017;55(1):139-144
pages 139-144 views