Email this article Phase transitions and fluctuations in classical statistical mechanics
- Authors: Martynov G.A.1
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Affiliations:
- Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 55, No 4 (2017)
- Pages: 611-614
- Section: Short Communications
- URL: https://journals.rcsi.science/0018-151X/article/view/157262
- DOI: https://doi.org/10.1134/S0018151X17040125
- ID: 157262
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Abstract
It is shown that allowance for fluctuations leads to the appearance of additional terms in the Hamiltonian of the system and in the thermodynamic parameters of the substance. As a result, it becomes possible to describe the critical phenomena and phase transitions of liquid–vapor within classical statistical mechanics (without taking into account fluctuations, this is impossible).
About the authors
G. A. Martynov
Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: g2302@migmail.ru
Russian Federation, Moscow, 119071
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