Influence of Synthesis Conditions on the Lifetime of Excess Charge Carriers in Monograin Powders with Kesterite Structure
- Autores: Gapanovich M.1, Varseev D.1,2, Rabenok E.1, Golovanov B.1, Novikov G.1,2
-
Afiliações:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Moscow State University
- Edição: Volume 53, Nº 6 (2019)
- Páginas: 429-434
- Seção: Photonics
- URL: https://journals.rcsi.science/0018-1439/article/view/157772
- DOI: https://doi.org/10.1134/S0018143919060079
- ID: 157772
Citar
Resumo
By solid-phase synthesis, macrocrystalline Cu2 − δZn2 − xSnxS4 − ySey monograin powders have been prepared, the chemical composition of which was shown by XRD and Raman spectroscopy to be different in powder fractions of different sizes formed during the synthesis. The influence of synthesis conditions on the decay kinetics of photogenerated charge carriers in different fractions has been studied using the frequency–time-resolved microwave photoconductivity method. The characteristic photoresponse half-life, τ1/2, increased with increasing grain size. The smallest values of the lifetime were observed for the fraction with sizes of 50–70 μm (τ1/2 <5 ns), and the largest values were for the fraction with a grain size of 70–90 μm (τ1/2 ~ 12 ns).
Palavras-chave
Sobre autores
M. Gapanovich
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gfnovikov@gmail.com
Rússia, Chernogolovka, Moscow oblast, 142432
D. Varseev
Institute of Problems of Chemical Physics, Russian Academy of Sciences; Moscow State University
Email: gfnovikov@gmail.com
Rússia, Chernogolovka, Moscow oblast, 142432; Moscow, 119991
E. Rabenok
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gfnovikov@gmail.com
Rússia, Chernogolovka, Moscow oblast, 142432
B. Golovanov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: gfnovikov@gmail.com
Rússia, Chernogolovka, Moscow oblast, 142432
G. Novikov
Institute of Problems of Chemical Physics, Russian Academy of Sciences; Moscow State University
Autor responsável pela correspondência
Email: gfnovikov@gmail.com
Rússia, Chernogolovka, Moscow oblast, 142432; Moscow, 119991