Email this article Exciplexes of Fluorinated and Methylated Derivatives of Dibenzoylmethanatoboron Difluoride with Benzene and Toluene on the Surface of Trimethylsilylated Aerosil
- Authors: Ionov D.S.1, Sazhnikov V.A.1, Yurasik G.A.1, Safonov A.A.1, Kononevich Y.N.2, Alfimov M.V.1,3
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Affiliations:
- Photochemistry Center, “Crystallography and Photonics” Federal Research Center, Russian Academy of Sciences
- Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Moscow Institute of Physics and Technology (State University)
- Issue: Vol 52, No 6 (2018)
- Pages: 485-491
- Section: Photonics
- URL: https://journals.rcsi.science/0018-1439/article/view/157535
- DOI: https://doi.org/10.1134/S0018143918060073
- ID: 157535
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Abstract
It has been shown that the introduction of electron-donating or electron-withdrawing groups in the para-position of dibenzoylmethanatoboron difluoride (DBMBF2) makes it possible to control the fluorescenсe characteristics of fluorophore exciplexes with methylbenzenes (MB). The fluorescent properties of DBMBF2/MB exciplexes at the gas–solid interface have been studied using the example of DBMBF2 adsorbed on the surface of trimethylsilylated aerosil.
About the authors
D. S. Ionov
Photochemistry Center, “Crystallography and Photonics” Federal Research Center, Russian Academy of Sciences
Author for correspondence.
Email: dmitriy.ionov@gmail.com
Russian Federation, Moscow, 119421
V. A. Sazhnikov
Photochemistry Center, “Crystallography and Photonics” Federal Research Center, Russian Academy of Sciences
Email: dmitriy.ionov@gmail.com
Russian Federation, Moscow, 119421
G. A. Yurasik
Photochemistry Center, “Crystallography and Photonics” Federal Research Center, Russian Academy of Sciences
Email: dmitriy.ionov@gmail.com
Russian Federation, Moscow, 119421
A. A. Safonov
Photochemistry Center, “Crystallography and Photonics” Federal Research Center, Russian Academy of Sciences
Email: dmitriy.ionov@gmail.com
Russian Federation, Moscow, 119421
Yu. N. Kononevich
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: dmitriy.ionov@gmail.com
Russian Federation, Moscow, 119991
M. V. Alfimov
Photochemistry Center, “Crystallography and Photonics” Federal Research Center, Russian Academy of Sciences; Moscow Institute of Physics and Technology (State University)
Email: dmitriy.ionov@gmail.com
Russian Federation, Moscow, 119421; Dolgoprudny, Moscow oblast, 141701
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