Email this article 1,4-dithiane radical cations in the CF3CCl3 matrix: Photoisomerization mechanism
- Authors: Sorokin I.D.1, Gromov O.I.1,2, Pergushov V.I.1, Melnikov M.Y.1
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Affiliations:
- Department of Chemistry
- N.N. Semenov Institute of Chemical Physics
- Issue: Vol 50, No 5 (2016)
- Pages: 362-367
- Section: Photochemistry
- URL: https://journals.rcsi.science/0018-1439/article/view/157041
- DOI: https://doi.org/10.1134/S0018143916050155
- ID: 157041
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Abstract
It has been established that the photoinduced process observed in EPR and in optical absorption spectra for 1,4-dithiane radical cations in the CF3CCl3 matrix at 77 K can be ascribed to a “boat”—“twist boat” conformational transition.
About the authors
I. D. Sorokin
Department of Chemistry
Author for correspondence.
Email: ivan.d.sorokin@gmail.com
Russian Federation, Leninskiye gory, 1/3, Moscow, 119991
O. I. Gromov
Department of Chemistry; N.N. Semenov Institute of Chemical Physics
Email: ivan.d.sorokin@gmail.com
Russian Federation, Leninskiye gory, 1/3, Moscow, 119991; Kosygina street, 4, Moscow, 119991
V. I. Pergushov
Department of Chemistry
Email: ivan.d.sorokin@gmail.com
Russian Federation, Leninskiye gory, 1/3, Moscow, 119991
M. Ya. Melnikov
Department of Chemistry
Email: ivan.d.sorokin@gmail.com
Russian Federation, Leninskiye gory, 1/3, Moscow, 119991
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