Calorimetric determination of the standard enthalpy of formation of stannite, Cu2FeSnS4


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The standard enthalpy of formation of stannite (Cu2FeSnS4) was calculated from the calorimetric measurements of the reactions of its formation from simple synthetic sulfides: Cu2S + FeS2 + SnS → Cu2FeSnS4 and 2CuS + FeS + SnS → Cu2FeSnS4. Using published data for the binary sulfides, the standard enthalpy of formation of stannite from the elements was determined as ΔfH°298.15(Cu2FeSnS4) =–(417.28 ± 2.28) kJ mol–1.

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T. Stolyarova

Institute of Experimental Mineralogy

Email: euo@iem.ac.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432

A. Baranov

Institute of Experimental Mineralogy; Faculty of Geology

Email: euo@iem.ac.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432; Moscow, 119991

E. Osadchii

Institute of Experimental Mineralogy

编辑信件的主要联系方式.
Email: euo@iem.ac.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432

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