Open Access Open Access  Restricted Access Access granted  Restricted Access Subscription Access

Vol 57, No 8 (2019)

Article

pages 835-836 views
pages 837-850 views

Theoretical Analysis of Mg and Si Chemical and Isotopic Fractionation at Vaporization of Ca–Al Inclusions of Chondrites

Yakovlev O.I., Shornikov S.I.

Abstract

Experimental study of changes in the composition of Ca–Al inclusions of chondrites during evaporation indicates the chemical and isotopic fractionation of this material are closely interrelated. The coupling is theoretically described using an equations for the evaporation rate of a component of melt (the Hertz–Knudsen equation) and Rayleigh isotope fractionation. The form of the Rayleigh equation (which was derived from the Hertz–Knudsen equation) conventionally used in the foreign literature faces difficulties in interpreting experimental data. The discrepancy between the experimental and model data is explained by the fact that the “ideal” isotope fractionation factor used in the Rayleigh equation does not take into account its dependence on the temperature and composition of the evaporating melt. The paper presents an alternative expression for the Rayleigh equation and a new expression of the Hertz–Knudsen evaporation rate with regard for the activity of melt components. The activity of the components is determined by the acidity–basicity index of the melt Ca–Al inclusion, which, in turn, affects the evaporative fractionation of Mg and Si isotopes.

Geochemistry International. 2019;57(8):851-864
pages 851-864 views

Thermodynamic Modeling of Evaporation Processes of Lunar and Meteorite Substance

Shornikov S.I.

Abstract

The paper suggests a thermodynamic approach to modeling the evaporation of lunar and meteorite matter. Comparison of the results of model calculations and experimental data demonstrates the high accuracy of the developed approach to description of thermodynamic properties of melts of lunar and meteorite substance and its behavior at evaporation. The observed relations of melt evaporation are consistent with the thermodynamic values characterizing the residual melts.

Geochemistry International. 2019;57(8):865-872
pages 865-872 views

Phosphorus-bearing Olivines of Lunar Rocks: Sources and Localization in the Lunar Crust

Demidova S.I., Anosova M.O., Kononkova N.N., Brandstätter F., Ntaflos T.

Abstract

Abstract—Fragments of P-bearing olivine have been studied in lunar highland, mare, and mingled meteorites and in “Apollo-14”, “Luna-16, -20, -24” lunar samples. The olivines contain up to 0.5 wt % P2O5 and have variable MG# numbers. They are associated with anorthite, pyroxene, and accessory spinel-group minerals, Ti and Zr oxides, phosphates, troilite, and Fe–Ni metal. Three possible sources of P-bearing olivine were found in the lunar material: 1) highland anorthositic–noritic–troctolitic rocks enriched in incompatible elements and interpreted to be related to high-Mg suite rocks: 2) late-stage products of mare basalts crystallization; and 3) unusual olivine–orthopyroxene intergrowths of meteoritic or lunar origin. Enrichment in incompatible elements may result from both crystallization processes (source 2) and KREEP assimilation (sources 1 and 3). However, superimposed metasomatic processes can lead to some addition of phosphorus and other elements. The rarity of P-bearing olivines points either to the low abundance or local distribution of their sources in the lunar crust. Association with mare basalts specifies the highland–mare boundary. The presence of evolved rocks in the studied breccias suggests a possible connection of some sources with recently discovered granitic domes in Procellarum Ocean. This means the P-bearing sources are mainly localized on the nearside of the Moon.

Geochemistry International. 2019;57(8):873-892
pages 873-892 views

Metal Crystallization in IIE Irons and Their Possible Meteorite Analogues

Teplyakova S.N., Lorenz C.A.

Abstract

The metal of IIE irons provides evidence of fractionation in the interiors of an asteroid, but their fine-grained structures are incompatible with their endogenous origin. It was proposed that the metal underwent remelting on the surface of the parent body. Data on the mineragraphy and on the mineral and chemical composition of IIE irons (Elga, Verkhnodniprovsk, Tobychan, Miles, and Watson) indicate that the relatively fine-grained metal structure and anhedral schreibersite grains were probably formed by crystallization from melt. According to the calculated data on the bulk composition of the Elga metal and on the Fe–Ni–P phase diagrams, the crystallization of the first γ-Fe grains began at ~1511°С and ended at ~1060–1100°С with the formation of centimeter-sized polygonal crystals of taenite and anhedral schreibersite grains along their boundaries. The identical composition of the anhedral schreibersite, both along the borders of the taenite grains and on the rims around nonmetallic inclusions, indicates that they were formed simultaneously. Among the four generations of schreibersite, the anhedral schreibersite is distinguished for its high Fe/Ni ratio. It was also noted that the higher the crystallization temperature of schreibersite, the lower its Ni content. Similar metal structures were found in other types of meteorites: in IAB irons and in the metal of some mesosiderites, whose impact-related origin is thought to be the most probable. Hence, the mechanism of formation of IIE irons by means of shock remelting of fractionated metal and mixing with silicate fragments on the surface of the parent body may have also produced other meteorite types.

Geochemistry International. 2019;57(8):893-902
pages 893-902 views

Liquid Immiscibility in Regions of Localized Shock-Induced Melting in the Elga Meteorite

Khisina N.R., Wirth R., Abdrakhimov A.M.

Abstract

Abstract—The regions of localized shock melting (melt pockets) in one of silicate inclusions in IIE Elga iron meteorite were investigated with EMPA, SEM, TEM and Raman spectroscopy. It has been established that the mechanism of formation of melt pockets in Elga is of a mixed nature, being associated not only with melting in situ of the silicate matrix, but also with the intrusion of portions of the melted schreibersite–oxide rim into the silicate inclusion. Melt pockets have an emulsion texture, which is a sign of phase separation by liquid immiscibility in high-temperature shock melts. The emulsion texture formed by droplet-shaped exsolutions of siderite in the schreibersite matrix of one of the melt pockets has all the features of phase separation by liquid immiscibility at superliquidus temperatures. This convincingly indicates the extraterrestrial origin of siderite in the Elga meteorite.

Geochemistry International. 2019;57(8):903-911
pages 903-911 views

Raman Spectroscopy of High-Pressure Phases in Shocked L6 Chondrite NWA 5011

Litasov K.D., Badyukov D.

Abstract

Abstract—The paper presents the results of studies of thick shock melt veins in the L6 chondrite NWA 5011. The veins contain a wide variety of high-pressure phases that correspond to contrast values of pressure–temperature parameters on equilibrium phase diagrams. Olivine was transformed to ringwoodite and wadsleyite, orthopyroxene to majorite, akimotoite, and bridgmanite glass, maskelynite is converted to jadeite (+SiO2) and lingunite, apatite to tuite, and chromite to the phase with the calcium ferrite (mCF-FeCr2O4) structure. The peak PT shock parameters for NWA 5011 seem to be the highest among the ones for other shocked chondrites according to the wide occurrence of lingunite and bridgmanite glass and are considerably higher than 25 GPa and 2500 K. Akimotoite crystals in a quenched matrix of the shock melt veins were found for the first time. Probably, they initially crystallized as bridgmanite, since akimotoite is not a liquidus phase in the related systems. Plagioclase–chromite aggregates have been established, which characterize the late stages of the shock process and are formed during successive crystallization from isolated pockets of the impact melt.

Geochemistry International. 2019;57(8):912-922
pages 912-922 views

Shock-Wave Experiment with the Chelyabinsk LL5 Meteorite: Experimental Parameters and the Texture of the Shock-Affected Material

Petrova E.V., Grokhovsky V.I., Kohout T., Muftakhetdinova R.F., Yakovlev G.A.

Abstract

A spherical geometry shock experiment with the light-colored lithology material of the Chelyabinsk LL5 ordinary chondrite was carried out. The material was affected by shock and thermal metamorphism whose grade ranged from initial stage S3-4 to complete melting. The temperature and pressure were estimated at >2000°С and >90 GPa. The textural shock effects were studied by optical and electron microscopy. A single experimental impact has produced the whole the range of shock pressures and temperatures and, correspondingly, four zones identified by petrographic analysis: (1) a melt zone, (2) a zone of melting silicates, (3) a black ring zone, and (4) a zone of weakly shocked initial material. The following textural features of the material were identified: displacement of the metal and troilite phases from the central melt zone; the development of a zone of mixed lithology (light-colored fragments in silicate melt); the origin of a dark-colored lithology ring; and the generation of radiating shock veinlets. The experimental sample shows four textural zones that correspond to the different lithology types of the Chelyabinsk LL5 meteorite found in fragments of the meteoritic shower in the collection at the Ural Federal University. Our results prove that shock wave loading experiment can be successfully applied in modeling of space shocks and can be used to experimentally model processes at the small bodies of the solar system.

Geochemistry International. 2019;57(8):923-930
pages 923-930 views

Meteorite Minerals

Ivanov A.V., Yaroshevskiy A.A., Ivanova M.A.

Abstract

“The Meteorite Minerals Catalog” is the first edition in Russia prepared in the 21st century. It includes all the minerals found in meteorites, approved by the Committee on New Minerals and MMA Mineral Names approved before January 1, 2017, and mineral phases. The Russian and English names, chemical compositions, and meteorites or meteorite groups characterized by the considered minerals are given for all minerals and mineral phases. Notably, the first descriptions of all minerals and phases and references to publications are also given in the Catalog. Minerals whose origin is associated with specific processes are also presented. These include pre-solar meteorite minerals, refractory and ultra-refractory solar condensates, impact minerals of meteorites and products of the terrestrial weathering of meteorites.

Geochemistry International. 2019;57(8):931-939
pages 931-939 views