Vol 56, No 2 (2018)

This study presents the results of petrographic, geochemical, and isotope geochronological analyses of rock samples from the Southern flank of the Vema transform fault (Atlantic), which were dredged on cruises 19-th and 22-nd of the R/V Akademik Nikolai Strakhov. The sample suite includes both fresh and metamorphosed gabbros, dolerites, serpentinites, metapyroxenites. Zircons separated from three gabbro samples recovered at three different stations were used for in situ U–Pb dating by LA-ICP-MS. The ages reveal a strong linear relationship with a distance from the axis of the Mid-Atlantic ridge, which allowed us to estimate the rate of spreading in this segment of the Mid-Atlantic Ridge. It can be concluded that the estimated spreading rate of 16.2 ± 0.8 mm/yr was constant over the past 15 Myr. The mutual consistency of all U-Pb zircon and ³⁹Ar–⁴⁰Ar amphibole ages (Cipriani et al., 2009) obtained from the sampled transect suggests the temporal continuity of magmatic events that led to the formation of the original gabbroic rocks and their transformation during subsequent metamorphism. Rb—Sr isotope data show that hydrothermal activity took place in the presence of seawater between 14.7 and 9 Ma in the spreading axis region. Variations in the Nd isotopic composition in the time sequence of magmatic events indicate a high degree of chemical and isotopic heterogeneity of the ascending mantle material which became later entrained in the melting region beneath a spreading zone. Melting of the sources with primitive mantle composition (ε_Nd ~ + 8 to +9) as well as enriched sources took place in the time interval between ~ 17 and 14.7 Ma and at about 8 Ma. The enriched source material is most likely represented by ancient mafic substratum.

The paper represents an algorithmic implementation of the SPINMELT-2.0 model designed to simulate Cr-spinel–melt equilibrium, and provides a description of its petrologic options. The properties of the SPINMELT-2.0 model were studied by modeling the topology of the liquidus surface of spinel and its dependence on pressure, redox potential, and concentrations of major components (including Cr₂O₃ and H₂O) in the melt. Reference simulations were carried out for primitive MORB tholeiite. The spinel composition is demonstrated to depend on variously (and often oppositely) acting factors. Providing an accurate estimate of a parental magma composition, the SPINMELT-2.0 program allows one to evaluate a range of P–T–fO₂–H₂ O parameters responsible for the composition of an original magmatic spinel. The SPINMELT program makes it possible not only to effectively correlate available independent petrological estimates but also to consciously correct them, which is particularly important when the composition of the model melts should be estimated. This is illustrated by the application of the model to data on the composition of rocks and minerals of two young volcanoes in Kamchatka: Tolbachik and Gorely.

Melting relations in the multicomponent diamond-forming systems of the upper mantle with a boundary of K–Na–Mg–Fe–Ca carbonate, phases of the model peridotite and eclogite, carbon, and titanium minerals from kimberlite (ilmenite FeTiO₃, perovskite CaTiO₃, and rutile TiO₂) were studied experimentally at 7–8 GPa and 1600–1650°C. Perovskite reacts with the formation of rutile in the diamond-forming silicate–carbonate melts. We discovered liquid immiscibility between melts of titanium minerals, on the one hand, and carbonate–carbon, peridotite–carbonate–carbon, and eclogite–carbonate–carbon diamond-forming melts, on the other. The solubility of titanium mineral in diamond-forming melts is negligible independent of their concentration in the experimental systems. Growth melts retain high diamond-forming efficiency. In general, the experimental results are evident for the xenogenic nature of titanium minerals in inclusions in diamond and, therefore, in diamond-forming melts. It is shown that the physicochemical factors that may correlate the diamond content with the concentration of Ti in kimberlite do not occur during the diamond genesis in silicate–carbonate–carbon parental melts containing titanium minerals and their melts.

During Cruise 62nd of the R/V “Professor Gagarinsky” in September, 2014, the carbonate system of sediments and contents of nutrients and organic carbon in pore water were studied in two geochemical stations located in hypoxia areas in the Peter the Great Bay. It was established that the concentrations of silica, phosphorus, and ammonium increase by 5, 10, and 20 times, respectively, with sediment depth to 70–80 cm. The alkalinity, dissolved inorganic carbon, and the partial pressure of carbon dioxide significantly increase with depth, while рН value and organic matter (ОM) decrease. Changes in the chemical composition of pore water with sediment depth (0–80 cm) are caused by anaerobic microbial degradation of OM, concentration of which in the top sediment layer is 2–3%. The degradation products of OM in the bottom waters of bay and pore waters of bottom sediments indicate that its main sources are diatoms. During hypoxia, the oxygen demand rate by sediment surface near Furugelm Island is estimated to be 5 mmol/(m² day). A combination of such factors as downwelling circulation, the absence of photosynthetically active radiation, and the high oxygen demand rate at the water/sediment interface provides hypoxia formation in the depressions of the Peter the Great Bay bottom topography.

The mineral composition, distribution and fractionation of rare-earth elements in dissolved and suspended forms (solid residue) of atmospheric precipitation were studied by analyzing the snow sampled over urbanized territory by the example of the city of Blagoveschensk. Electron-microscopic studies revealed the own minerals of rare-earth elements in dust aerosols. It is shown that the main sources of the atmospheric pollution by rare-earth elements were emissions of TPP (heat and power plants) and boiler houses. Contrasting geochemical anomalies of rare-earth elements were found in the snow cover of the city. The REE concentrations in the solid phase of snow are few orders of magnitude higher than those of the liquid phase. The snow solid phase provides insight into the REE behavior, because it directly reflects the impact of different anthropogenic sources. The characteristic feature of the REE distribution in the solid residue of snow is their LREE enrichment relative to MREE and HREE. The average HREE content is 10% of total REE. In the snow water–solid phase system, most samples show weak fractionation between LREE and HREE owing to the low total mineralization of the snow liquid phase and the small content of organic matter.