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Vol 56, No 11 (2018)

Article

Early Cretaceous Alkaline Magmatism of East Antarctica: Peculiarities, Conditions of Formation, and Relationship with the Kerguelen Plume

Sushchevskaya N.M., Belyatsky B.V., Tkacheva D.A., Leitchenkov G.L., Kuzmin D.V., Zhilkina A.V.

Abstract

Generalization of available literature and new original data showed that the Early Cretaceous high-Mg alkaline magmatism is confined to the ancient Lambert rift zone. Alkaline ultramafic rocks developed in the areas of this zone (Jetty Oasis, western flank of the Beaver and Radok lakes, Fisher and Meredith massifs) were derived through melting of metasomatized continental mantle at ~1270°С and at depths of 130–140 km. Variations of major and trace-element composition and the wide range in olivine composition (Fo91–Fo80) are consistent with its change through intrachamber crystallization. The average values of initial isotope composition of ultra-alkaline high-Mg basalts are as follows: 143Nd/144Nd—0.512485, 87Sr/86Sr—0.70637, 207Pb/204Pb—15.671, 206Pb/204Pb—18.391, 208Pb/204Pb—38.409. They are close to the model ЕМII source and can be arbitrarily taken as the preliminary assessment of isotope composition of a source of Mesozoic melts. Based on lithophile element and isotope compositions, the alkaline high-Mg basaltic magmatism is thought to be related to the thermal impact of the Kerguelen plume on the lithospheric mantle of East Gondwana 120–110 Ma. Similar ancient deep-seated metasomatized eastern Gondwanan mantle, which contains carbonates and biotite and has an age of 2.4 Ga, was found in southern East Antarctica as well as in the north within eastern India.

Geochemistry International. 2018;56(11):1051-1070
pages 1051-1070 views

Fine-Grained Scoriaceous and Unmelted Micrometeorites: Sources and Relationships with Cosmic Spherules

Badyukov D.D., Brandstaetter F., Topa D.

Abstract

185 fine-grained micrometeorites (FgMMs) from the Novaya Zemlya micrometeorite collection were studied to elucidate the sources of cosmic dust. The compositions of the micrometeorites were compared with those of carbonaceous chondrites and cosmic spherules. FgMMs were weakly or moderately heated when decelerated in the atmosphere, and some of them thereby retained their original textures (unmelted FgMMs), while others consist mostly of porous degassing products of phyllosilicates (scoriaceous FgMMs). According to the composition of their matrix, we divide the FgMMs into two groups: high- and low-Fe. The textures and compositions of the FgMMs are generally similar to those of the matrix of carbonaceous chondrites. The FgMM group with high-Fe matrix corresponds to the composition of CI, CM, CO, and CR chondrites, which may have been a source of these meteorites. Conversely, the low-Fe group of FgMMs differs from chondrites of these groups and is likely related to the carbonate-poor matrix of the Tagish Lake carbonaceous chondrite or is presented by a material that is still absent from meteorite collections. We have compared the compositions of the FgMMs with the compositions of various types of cosmic spherules (CSs), which were produced by melting of micrometeoroids (cosmic dust particles) at their deceleration in the atmosphere. Both original and published data on CS compositions are used. Porphyritic and barred textural varieties of CSs could have been produced from micrometeoroids similar in the compositions to the high-Fe FgMMs, whereas low-Fe micrometeoroids might have been precursors of cryptocrystalline and glass CSs.

Geochemistry International. 2018;56(11):1071-1083
pages 1071-1083 views

Sites and Origin of Noble Gases in Minerals: A Case Study of Amphibole from Alkaline Granitoids of the Kola Peninsula

Gannibal M.A., Tolstikhin I.N., Verchovsky A.B., Skiba V.I., Vetrin V.R., Gudkov A.V.

Abstract

The paper presents newly acquired data on the budget and mobility of isotopes of noble gases in samples of amphibole, a mineral commonly characterized by relatively high He concentrations compared to other rock-forming minerals of Earth’s crust. In the amphibole samples from alkaline granites of the Ponoy Massif, Kola Peninsula, 3He, 4Не, and 40Ar* isotopes were mostly radiogenic, generated by radioactive decay and nuclear reactions. Retention ability of two helium isotopes was found to be different: since the time of metamorphic event approximately 38% 3Не and only approximately 16% 4Не have been preserved. A small He fraction (≈3% of its total concentration) and a larger part of radiogenic 40Ar* (≈35%) are hosted in fluid inclusions. Relatively high 3Не/4He ratios (up to ≈1 × 10–6) in the amphibole were caused by the high Li concentrations and better preservation of 3Не. The 3He/4He ratios in helium extracted from the samples by melting and crushing are indistinguishable, while the 4He/40Ar* ratios in the fluid inclusions (opened by sample crushing) (~0.6) are notably lower than those in the bulk samples (melting) (5) and those calculated from the U, Th, and K concentrations (15). Two He release peaks were observed on the curves of rapid (12–40°C min–1) liner heating of the samples. At a lower heating rate (~5°C min–1), the high-temperature peak disappeared. Further investigation of this peculiarity of He migration has shown that (1) it is also typical of some other amphibole samples (not only those from Ponoy granites); (2) He amount in the “disappearing” peak varies from sample to sample and also depends on the heating rate and grain size (powdered samples with an average grain size of ≤50 µm did not yield the second peak, regardless of the heating rate); (3) the temperature of He release from powdered samples is approximately 50°C lower than that for mineral grains; and (4) preliminary long-term heating of the sample to 400°C (a temperature at which He starts to diffuse from the amphibole structure) results in a significant decrease in the low-temperature peak and a shift of the “disappearing” peak toward lower temperatures. The probable reasons for this phenomenon are discussed.

Geochemistry International. 2018;56(11):1084-1092
pages 1084-1092 views

Ferromanganese Crusts in the South Atlantic Ocean: Compositional Evolution and Specific Features of Ore Formation

Dubinin A.V., Rimskaya-Korsakova M.N., Berezhnaya E.D., Uspenskaya T.Y., Dara O.M.

Abstract

Abstract—Layer-by-layer chemical and mineralogical analysis was carried out to consider the evolution of the Fe–Mn crusts in different tectonic settings in the South Atlantic Ocean. The ferromanganese crust in the rift valley of the Mid-Atlantic Ridge was formed owing to the hydrothermal–hydrogenetic supply. The formation of crust in the Transform Fracture zones of the Angola Basin was related to the halmyrolysis of magmatic rocks and subsequent hydrogenetic supply, which affected the proportions of goethite and vernadite, the Mn/Fe ratio, and Ce anomaly, as well as the content of some elements (Co, Cu, Al, REE). It is revealed that the Fe–Mn crusts taken in the abyssal part and on the seamount top in the Cape Basin are hydrogenetic in origin and consist of vernadite significantly enriched in Co, Ce, Tl, and Pt. The relationship of trace elements with manganese minerals is estimated by leaching of crusts by reagents, which either completely dissolve manganese oxyhydroxides (1 M NH2OH · HCl + 25%CH3COOH) or no (3.5 N H2SO4). It was shown that 100% Co and only 28% Ce are incorporated in the manganese minerals, while REE, Y, Sr, and U form a sorption complex of oxhyhydroxides. To estimate the chemical peculiarities of the hydrogenetic Fe–Mn crusts of the Atlantic Ocean, they were compared with the crusts of the Pacific Ocean. It is shown that the crusts of the Pacific Ocean have higher manganese and cobalt contents. The additional manganese could be derived from a hydrothermal source.

Geochemistry International. 2018;56(11):1093-1108
pages 1093-1108 views

Quartz Solubility in the Vapor Phase of the H2O–HF System at 200°С and Saturated Vapor Pressure: Experimental Data

Konyshev A.A., Aksyuk A.M., Korzhinskaya V.S.

Abstract

Abstract—This work was carried out to elucidate the silica transport in the presence of fluorine at the low-temperature hydrothermal stage. The liquid-vapor distribution of fluorine in the HF–H2O system under saturated vapor pressure at 150 and 200°С as well as the dissolution of quartz in the vapor phase of the same system at 200°С and under saturated vapor pressure were studied. It is established that fluorine at 150–200°С is mainly partitioned in a a liquid phase, while its liquid/vapor distribution coefficient (Kd) is lower at 200°С than at 150°С in the region of high mHF concentrations. Quartz solubility in the vapor phase HF–H2O as compared to the pure water vapor at 0.1 mHF increases by more than four orders of magnitude and approaches quartz solubility in liquid water.

Geochemistry International. 2018;56(11):1109-1115
pages 1109-1115 views