Vol 54, No 11 (2016)

The ultrabasic–basic magmatic evolution of the lower mantle material includes important physicochemical phenomena, such as the stishovite paradox and the genesis of superdeep diamonds. Stishovite SiO₂ and periclase–wüstite solid solutions, (MgO · FeO)_ss, associate paradoxically in primary inclusions of superdeep lower mantle diamonds. Under the conditions of the Earth’s crust and upper mantle, such oxide assemblages are chemically impossible (forbidden), because the oxides MgO and FeO and SiO₂ react to produce intermediate silicate compounds, enstatite and ferrosilite. Experimental and physicochemical investigations of melting phase relations in the MgO–FeO–SiO₂–CaSiO₃ system at 24 GPa revealed a peritectic mechanism of the stishovite paradox, (Mg, Fe)SiO₃ (bridgmanite) + L = SiO₂ + (Mg, Fe)O during the ultrabasic–basic magmatic evolution of the primitive oxide–silicate lower mantle material. Experiments at 26 GPa with oxide–silicate–carbonate–carbon melts, parental for diamonds and primary inclusions in them, demonstrated the equilibrium formation of superdeep diamonds in association with ultrabasic, (Mg, Fe)SiO₃ (bridgmanite) + (MgO · FeO)_ss (ferropericlase), and basic minerals, (FeO · MgO)_ss (magnesiowüstite) + SiO₂ (stishovite). This leads to the conclusion that a peritectic mechanism, similar to that responsible for the stishovite paradox in the pristine lower mantle material, operates also in the parental media of superdeep diamonds. Thus, this mechanism promotes both the ultrabasic–basic evolution of primitive oxide–silicate magmas in the lower mantle and oxide–silicate–carbonate melts parental for superdeep diamonds and their paradoxical primary inclusions.

Olivine-bearing varieties of garnet–clinopyroxene crystalline schists of the Lapland granulite belt have been studied in detail for the first time. Two types of olivine (iron mole fractions of 27 and 38%) are distinguished. Olivine with lower Fe content occurs as inclusions in clino- and orthopyroxene and in terms of СаО and Cr contents is close to magmatic minerals. Olivine with high Fe content presumably suffered highand moderate-temperature metamorphism. The olivine-bearing rocks contain several grains of omphacite with 30–37 mol % jadeite and garnet with 44–50 mol % pyrope, which can be regarded as relict assemblages of the early stage of eclogitization of a magmatic protolith. The presence of symplectites indicates their retrograde transformation during decompression. The protoliths of the studied rocks could be olivine gabbronorites and pyroxenites. It was found that the rocks contain high-alumina minerals: corundum, spinel, and sapphirine. In addition, Al₂O₃ content in some amphibole grains is as high as 19 wt %. This indicates that the ascent of the deep-seated rocks was accompanied by interaction with Al-rich fluid. The positive Eu anomaly in the olivine-bearing rocks and some of their minerals is indicative of the reducing character of fluid. Activation of fluid reworking leading to the formation and transformation of the olivine-bearing rocks, transfer of alumina and its precipitation at different depths are related to the processes at the base of the Paleoproterozoic rift system of Karelides.

This study presents the analysis of correlation between trace element compositions of caustobioliths (oils, coals, oil and black shales), upper and lower continental crust, and living matter. It was shown that trace element concentrations in coals and oil shales have the better correlation with the upper crustal values, whereas trace elements in oils correlate well with the lower crustal values. The statistically significant, yet poorer correlation was observed for trace element compositions of oils and living matter as compared to correlations between oils and lower crust. The results suggest that oils are compositionally more homogeneous on a basin scale and possibly have more heterogeneous composition in different petroleum basins. A suite of characteristic trace elements (Cs, Rb, K, U, V, Cr, and Ni) that was used for analysis allowed a consistent interpretation of the relative upper and lower crustal contributions to the trace element composition of oils.

The paper presents data on the distribution of tritium, a hydrogen radioactive isotope, in the snow cover of mid-taiga landscapes in central Yakutia. Regional tritium escape to the atmosphere in the late 20th century and its accumulation in the snow cover resulted from regional atmospheric transfer and corresponded to the concentration of this isotope in the snow cover at the South Pole. Tritium concentration in the snow cover had almost tripled by 2013. Tritium concentration in the snow cover is correlated with the human population of the settlement zone. The long-term anthropogenic contamination in the area is caused first of all by atmospheric fallouts of radioactive products of the 2011 Fukushima accident.