Heterogeneous Equilibria in Saturated Aqueous Solutions of Uranophane

Abstract

Heterogeneous equilibria in the system Ca(HSiUO₆)₂ · 5H2O_(c)–aqueous solution were studied over broad ranges of pH, ionic strength, and ionic composition of the solution, and the pH range of stability of Ca uranyl silicate is determined. Hydrolysis products of Ca uranyl silicate are identified, and their solubility is determined. The equilibrium constant of the dissolution reaction and the standard Gibbs function of formation of Ca(HSiUO₆)₂ · 5H₂O are calculated from experimental data, and solubility curves of uranophane and equilibrium speciation diagrams for U(VI), Si(IV), and Ca(II) in coexisting aqueous solutions and solid phases are calculated.