Thermochemical study Mg–Fe amphiboles

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Abstract

The paper presents data on the thermochemical study (high-temperature melt calorimetry in a Tian–Calvet microcalorometer) of two natural Mg–Fe amphiboles: anthophyllite Mg2.0(Mg4.8Fe0.22+)[Si8.0O22](OH)2 from Kukh-i-Lal, southwestern Pamirs, Tajikistan, and gedrite Na0.4Mg2.0(Mg1.7Fe0.22+Al1.3)[Si6.3Al1.7O22](OH)2 from the Kola Peninsula, Russia. The enthalpy of formation from elements is obtained as–12021 ± 20 kJ/mol for anthophyllite and as–11545 ± 12 kJ/mol for gedrite. The standard entropy, enthalpy, and Gibbs energy of formation are evaluated for Mg–Fe amphiboles of theoretical composition.

About the authors

L. P. Ogorodova

Geological Faculty

Author for correspondence.
Email: logor@geol.msu.ru
Russian Federation, Moscow, 119991

I. A. Kiseleva

Geological Faculty

Email: logor@geol.msu.ru
Russian Federation, Moscow, 119991

M. F. Vigasina

Geological Faculty

Email: logor@geol.msu.ru
Russian Federation, Moscow, 119991

L. V. Mel’chakova

Geological Faculty

Email: logor@geol.msu.ru
Russian Federation, Moscow, 119991

D. A. Ksenofontov

Geological Faculty

Email: logor@geol.msu.ru
Russian Federation, Moscow, 119991

I. A. Bryzgalov

Geological Faculty

Email: logor@geol.msu.ru
Russian Federation, Moscow, 119991

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