Physicochemical model of tin behavior in weathering profiles


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Abstract

Numerical simulations of a weathering profile on granite containing 10–8 mol/L Sn (whose average content in the Earth’s crust is 0.00025%) by the SELECTOR program package indicate that cassiterite SnO2 solubility under both oxidizing and reducing conditions is no higher than 10–10 mol/L within the pH range of 3 to 11. The only ion occurring in equilibrium with cassiterite is the neutral Sn(OH)4(aq)0 complex, which was detected in both oxidizing and reducing environments.

About the authors

V. A. Kopeikin

Ukhta State Technical University

Author for correspondence.
Email: vkopeikin@ugtu.net
Russian Federation, Ukhta, 169300

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