The Magnetocaloric Effect in La(Fe,Mn,Si) 13 H  x   Based Composites: Experiment and Theory

A. P. Kamantsev; Каманцев А. П.; A. A. Amirov; Амиров А. А.; D. M. Yusupov; Юсупов Д. М.; A. V. Golovchan; Головчан А. В.; O. E. Kovalev; Ковалёв О. Е.; A. S. Komlev; Комлев А. С.; A. M. Aliev; Алиев А. М.

doi:10.31857/S001532302360106X

The Magnetocaloric Effect in La(Fe,Mn,Si)₁₃H_x Based Composites: Experiment and Theory

Autores: Kamantsev A.¹^,2, Amirov A.³, Yusupov D.³, Golovchan A.¹^,4, Kovalev O.¹^,4, Komlev A.², Aliev A.³
Afiliações:
1. Kotelnikov Institute of Radioengineering and Electronics, Russian Academy of Sciences
2. Lomonosov Moscow State University
3. Amirkhanov Institute of Physics DFRC RAS
4. Galkin Donetsk Institute for Physics and Engineering
Edição: Volume 124, Nº 11 (2023)
Páginas: 1074-1085
Seção: ЭЛЕКТРИЧЕСКИЕ И МАГНИТНЫЕ СВОЙСТВА
URL: https://journals.rcsi.science/0015-3230/article/view/232708
DOI: https://doi.org/10.31857/S001532302360106X
EDN: https://elibrary.ru/CEEPZW
ID: 232708

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Abstract—

Samples of composites with different porosity and surface roughness based on LaFe_11.4Mn_0.3Si_1.3H_1.6 (LFMSH) alloy powders were obtained, their magnetocaloric properties were studied by a direct method in cyclic magnetic fields μ₀H = 1.2 T at a frequency of 2 Hz. The maximum value of the adiabatic temperature change in pure LFMSH powder was ΔT = 3 K at Т₀ = 287 K in the sample cooling mode; for composite samples, this value turned out to be approximately 2 times lower than in the powder. The effect of Mn and H atoms on the electronic structure and local magnetic characteristics of the initial La(Fe,Si)₁₃ alloy has been studied by the methods of the electron density functional theory. Replacing some of the Fe atoms with Mn reduces the total magnetic moment and slightly lowers the Curie temperature. Hydrogenation, on the contrary, leads to an increase in exchange interactions between Fe atoms located at the vertices of the icosahedron and an increase in the Curie temperature.

Palavras-chave

magnetocaloric effect, high magnetic fields, exchange interaction

Bibliografia

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