X-Ray Structure and PMR Spectra of Polycaproamide Modified by a Polyfluorinated Alcohol


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Resumo

Effects on polycaproamide structure of a polyfluorinated alcohol immobilized on montmorillonite clay nanoparticles were studied using x-ray structure analysis and broad-line PMR spectroscopy. An exfoliated composite formed and caused the crystal and molecular structures of this heterochain polymer to reorganize. A composite based on the polyfluorinated alcohol changed the mobility of macromolecular chain segments and increased the fraction of planar trans-conformations.

Sobre autores

S. Kudashev

Volgograd State Technical University

Autor responsável pela correspondência
Email: kudashev-sv@yandex.ru
Rússia, Volgograd

N. Zhuravlev

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Email: kudashev-sv@yandex.ru
Rússia, Ekaterinburg

V. Shapovalov

V. A. Belyi Metal-Polymer Research Institute, National Academy of Sciences of Belarus

Email: kudashev-sv@yandex.ru
Belarus, Gomel

T. Denisova

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences

Email: kudashev-sv@yandex.ru
Rússia, Ekaterinburg

A. Valenkov

Gomel State Medical University

Email: kudashev-sv@yandex.ru
Belarus, Homieĺ

V. Zheltobryukhov

Volgograd State Technical University

Email: kudashev-sv@yandex.ru
Rússia, Volgograd

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