X-Ray Structure and PMR Spectra of Polycaproamide Modified by a Polyfluorinated Alcohol

S. V. Kudashev; N. A. Zhuravlev; V. M. Shapovalov; T. A. Denisova; A. M. Valenkov; V. F. Zheltobryukhov

doi:10.1007/s10692-019-10037-0

X-Ray Structure and PMR Spectra of Polycaproamide Modified by a Polyfluorinated Alcohol

Authors: Kudashev S.V.¹, Zhuravlev N.A.², Shapovalov V.M.³, Denisova T.A.², Valenkov A.M.⁴, Zheltobryukhov V.F.¹
Affiliations:
1. Volgograd State Technical University
2. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences
3. V. A. Belyi Metal-Polymer Research Institute, National Academy of Sciences of Belarus
4. Gomel State Medical University
Issue: Vol 51, No 1 (2019)
Pages: 9-13
Section: Article
URL: https://journals.rcsi.science/0015-0541/article/view/235642
DOI: https://doi.org/10.1007/s10692-019-10037-0
ID: 235642

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Abstract

Effects on polycaproamide structure of a polyfluorinated alcohol immobilized on montmorillonite clay nanoparticles were studied using x-ray structure analysis and broad-line PMR spectroscopy. An exfoliated composite formed and caused the crystal and molecular structures of this heterochain polymer to reorganize. A composite based on the polyfluorinated alcohol changed the mobility of macromolecular chain segments and increased the fraction of planar trans-conformations.