Email this article Hybrid Composites of Hydrogels of Natural Cellulose with Electron-Excess Binuclear Zn(II) 1,10-Phenanthrocyanine. Immobilization of the Zinc Complexes in Cellulose Hydrgels and the Functional Composition of the Resultant Compounds
- Authors: Demidov V.N.1, Mikhalidi A.M.2, Vlasova E.N.2, Kotel’nikova N.E.2
-
Affiliations:
- Pro-Bright, St. Petersburg State University
- St. Petersburg State University of Industrial Technology and Design, Institute of High-Molecular-Weight Compounds, Russian Academy of Sciences
- Issue: Vol 50, No 5 (2019)
- Pages: 383-390
- Section: Reports to the Fourth International Conference on Current Trends in the Chemistry and Technology of Polymer Materials, St. Petersburg, 2018
- URL: https://journals.rcsi.science/0015-0541/article/view/235994
- DOI: https://doi.org/10.1007/s10692-019-09994-3
- ID: 235994
Cite item
Open Access
Access granted
Subscription Access
Abstract
New composites are obtained in the diffusion-adsorption immobilization of electron-excess zinc(II) 1,10-phenanthrocyanine complexes [(phen)nZn(μ-phencyanine)Zn(phen)n(OAc)4∙HOAc] (n = 0-2) in a 3D structure of super-swelling cellulose hydrogels. A mechanism is proposed for the immobilization of the zinc complexes in the hydrogel structure. The functional and chemical composition of the composites was studied in detail using Fourier transform IR spectroscopy. The immobilization of the complexes in the hydrogels structure was found to lead to their chemical reaction with cellulose in the hydrogel matrix.
About the authors
V. N. Demidov
Pro-Bright, St. Petersburg State University
Email: amikhalidi@yahoo.com
Russian Federation, St. Petersburg
A. M. Mikhalidi
St. Petersburg State University of Industrial Technology and Design, Institute of High-Molecular-Weight Compounds, Russian Academy of Sciences
Author for correspondence.
Email: amikhalidi@yahoo.com
Russian Federation, St. Petersburg
E. N. Vlasova
St. Petersburg State University of Industrial Technology and Design, Institute of High-Molecular-Weight Compounds, Russian Academy of Sciences
Email: amikhalidi@yahoo.com
Russian Federation, St. Petersburg
N. E. Kotel’nikova
St. Petersburg State University of Industrial Technology and Design, Institute of High-Molecular-Weight Compounds, Russian Academy of Sciences
Email: amikhalidi@yahoo.com
Russian Federation, St. Petersburg
Supplementary files
