Variation of Parameters of Organochlorine Compounds, Whiteness, and Absorption Spectra During Multistage Bleaching of Cellulose
- Authors: Koksharov A.V.1, Derkacheva O.Y.2, Sukhov D.A.2, Novikov E.M.2, Leiman V.I.2
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Affiliations:
- AO Group “Ilim”, 165651 Koryazhma
- Higher School of Technology and Energetics, St. Petersburg State University of Technologies and Design
- Issue: Vol 50, No 3 (2018)
- Pages: 215-218
- Section: Article
- URL: https://journals.rcsi.science/0015-0541/article/view/235385
- DOI: https://doi.org/10.1007/s10692-018-9963-6
- ID: 235385
Cite item
Abstract
The results of physicochemical and spectroscopic investigations of deciduous sulfate cellulose at various stages of ECF bleaching are presented. Significant changes in whiteness, the content of organochlorine compounds (OCC), the intensity of absorption bands for the conjugated and unconjugated CP%O groups at the first stages of bleaching, and their stabilization at later stages are demonstrated. The weak effect of multistage bleaching on the structure of the cellulose is demonstrated. Calibration models were constructed for rapid assessment of the parameters of the OCCs and whiteness from the IR spectra.
About the authors
A. V. Koksharov
AO Group “Ilim”, 165651 Koryazhma
Email: derkachevaou@rambler.ru
Russian Federation, Arkhangelsk Region
O. Yu. Derkacheva
Higher School of Technology and Energetics, St. Petersburg State University of Technologies and Design
Author for correspondence.
Email: derkachevaou@rambler.ru
Russian Federation, St. Petersburg
D. A. Sukhov
Higher School of Technology and Energetics, St. Petersburg State University of Technologies and Design
Email: derkachevaou@rambler.ru
Russian Federation, St. Petersburg
E. M. Novikov
Higher School of Technology and Energetics, St. Petersburg State University of Technologies and Design
Email: derkachevaou@rambler.ru
Russian Federation, St. Petersburg
V. I. Leiman
Higher School of Technology and Energetics, St. Petersburg State University of Technologies and Design
Email: derkachevaou@rambler.ru
Russian Federation, St. Petersburg
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