Variation of Parameters of Organochlorine Compounds, Whiteness, and Absorption Spectra During Multistage Bleaching of Cellulose


Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

The results of physicochemical and spectroscopic investigations of deciduous sulfate cellulose at various stages of ECF bleaching are presented. Significant changes in whiteness, the content of organochlorine compounds (OCC), the intensity of absorption bands for the conjugated and unconjugated CP%O groups at the first stages of bleaching, and their stabilization at later stages are demonstrated. The weak effect of multistage bleaching on the structure of the cellulose is demonstrated. Calibration models were constructed for rapid assessment of the parameters of the OCCs and whiteness from the IR spectra.

About the authors

A. V. Koksharov

AO Group “Ilim”, 165651 Koryazhma

Email: derkachevaou@rambler.ru
Russian Federation, Arkhangelsk Region

O. Yu. Derkacheva

Higher School of Technology and Energetics, St. Petersburg State University of Technologies and Design

Author for correspondence.
Email: derkachevaou@rambler.ru
Russian Federation, St. Petersburg

D. A. Sukhov

Higher School of Technology and Energetics, St. Petersburg State University of Technologies and Design

Email: derkachevaou@rambler.ru
Russian Federation, St. Petersburg

E. M. Novikov

Higher School of Technology and Energetics, St. Petersburg State University of Technologies and Design

Email: derkachevaou@rambler.ru
Russian Federation, St. Petersburg

V. I. Leiman

Higher School of Technology and Energetics, St. Petersburg State University of Technologies and Design

Email: derkachevaou@rambler.ru
Russian Federation, St. Petersburg

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2018 Springer Science+Business Media, LLC, part of Springer Nature