Chemical Copper Coating of Lavsan Fibers


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Abstract

A method for chemical deposition of thin copper coatings on lavsan fibers was developed using reduction of copper salts in alkaline solution in the presence of complexants. Sodium borohydride was used as the reductant. A nondestructive method for preliminary modification of the lavsan fibers with surface polar groups was found. Studies of the effect of the copper-salt anion on fiber metallization found that the use of copper acetate was most effective. X-ray phase analysis and electron-probe microanalysis found that the formed coating consisted of pure copper without impurities of oxides or other elements. SEM studies of the surface morphology of the copper-coated fibers showed that the obtained continuous coating consisted of Cu crystal agglomerates of dimensions ~500 nm. The metallized lavsan fibers had high electrical conductivity.

About the authors

N. I. Pakuro

Branch of L. Ya. Karpov Scientific Research Institute of Physics and Chemistry; Federal State Research and Design Institute of Rare Metal Industry

Author for correspondence.
Email: pakuro@cc.nifhi.ac.ru
Russian Federation, Moscow; Moscow

L. F. Rybakova

Branch of L. Ya. Karpov Scientific Research Institute of Physics and Chemistry

Email: pakuro@cc.nifhi.ac.ru
Russian Federation, Moscow

B. I. Nakhmanovich

Branch of L. Ya. Karpov Scientific Research Institute of Physics and Chemistry

Email: pakuro@cc.nifhi.ac.ru
Russian Federation, Moscow

A. K. Karaev

Institute of Engineering Physics

Email: pakuro@cc.nifhi.ac.ru
Russian Federation, Serpukhov

N. V. Sadovskaya

Branch of L. Ya. Karpov Scientific Research Institute of Physics and Chemistry

Email: pakuro@cc.nifhi.ac.ru
Russian Federation, Moscow

E. D. Politova

Branch of L. Ya. Karpov Scientific Research Institute of Physics and Chemistry

Email: pakuro@cc.nifhi.ac.ru
Russian Federation, Moscow

V. P. Sitnikov

Institute of Engineering Physics

Email: pakuro@cc.nifhi.ac.ru
Russian Federation, Serpukhov

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