Explosive Reduction of Graphite Oxide by Hydrazine Vapor at Room Temperature
- Authors: Gudkov M.V.1, Gorenberg A.Y.1, Shchegolikhin A.N.2, Shashkin D.P.1, Mel’nikov V.P.1
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Affiliations:
- Semenov Institute of Chemical Physics
- Emanuel Institute of Biochemical Physics
- Issue: Vol 478, No 1 (2018)
- Pages: 11-14
- Section: Physical Chemistry
- URL: https://journals.rcsi.science/0012-5016/article/view/153811
- DOI: https://doi.org/10.1134/S0012501618010037
- ID: 153811
Cite item
Abstract
Explosive reduction of graphite oxide aerogel at the moment of its contact with hydrazine vapor at room temperature was described. It was shown that the characteristics of the materials produced by explosive reduction of graphite oxide under thermal shock and under the action of hydrazine are virtually identical. This suggests the thermal nature of the explosion, which is initiated by an abrupt increase in the temperature of the surface of aerogel particles as a result of highly exothermic reactions of functional groups of graphite oxides with hydrazine. The composition and amount of gaseous products released at the moment of the explosive decomposition were estimated.
About the authors
M. V. Gudkov
Semenov Institute of Chemical Physics
Email: melnikov@chph.ras.ru
Russian Federation, Moscow, 119991
A. Ya. Gorenberg
Semenov Institute of Chemical Physics
Email: melnikov@chph.ras.ru
Russian Federation, Moscow, 119991
A. N. Shchegolikhin
Emanuel Institute of Biochemical Physics
Email: melnikov@chph.ras.ru
Russian Federation, Moscow, 119334
D. P. Shashkin
Semenov Institute of Chemical Physics
Email: melnikov@chph.ras.ru
Russian Federation, Moscow, 119991
V. P. Mel’nikov
Semenov Institute of Chemical Physics
Author for correspondence.
Email: melnikov@chph.ras.ru
Russian Federation, Moscow, 119991
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