Modeling of Low-temperature oxidation and combustion of droplets


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Key features of radiation extinguishing of spherical hot flame around a single droplet with its subsequent low-temperature oxidation and combustion under microgravity conditions—a phenomenon discovered in experiments onboard the International Space Station—have been reproduced using the mathematical model of droplet combustion and detailed kinetic mechanism of n-heptane oxidation and combustion. It has been demonstrated that experimentally observed repeated temperature flashes were blue flame flashes, and their duration was determined by the hydrogen peroxide decomposition time. In addition to this phenomenon, calculations predict the existence of new modes of low-temperature oxidation and combustion of droplets without the hot flame stage. In such modes, the basic reaction is concentrated very close to the droplet surface, and fuel vapor reacts in it only partially.

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S. Frolov

Semenov Institute of Chemical Physics; National Research Nuclear University MEPhI

编辑信件的主要联系方式.
Email: smfrol@chph.ras.ru
俄罗斯联邦, ul. Kosygina 4, Moscow, 1119991; Kashirskoe sh. 31, Moscow, 115409

V. Basevich

Semenov Institute of Chemical Physics

Email: smfrol@chph.ras.ru
俄罗斯联邦, ul. Kosygina 4, Moscow, 1119991

S. Medvedev

Semenov Institute of Chemical Physics

Email: smfrol@chph.ras.ru
俄罗斯联邦, ul. Kosygina 4, Moscow, 1119991

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