Heat Capacity and Thermodynamic Properties of SmFeGe2O7 in the Range 350–1000 K


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Abstract

SmFeGe2O7 germanate has been synthesized by solid-state reactions from stoichiometric mixtures of starting oxides using multistage sintering in the temperature range 1273‒1473 K. The effect of temperature on the heat capacity of the compound has been studied by differential scanning calorimetry. On the basis of the dependence Cp = f(T), the thermodynamic properties of this compound have been calculated.

About the authors

L. T. Denisova

Institute of Nonferrous Metals and Materials Science, Siberian Federal University

Author for correspondence.
Email: antluba@mail.ru
Russian Federation, Krasnoyarsk, 660041

A. D. Izotov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: antluba@mail.ru
Russian Federation, Moscow, 119991

Yu. F. Kargin

Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences

Email: antluba@mail.ru
Russian Federation, Moscow, 119991

L. A. Irtyugo

Institute of Nonferrous Metals and Materials Science, Siberian Federal University

Email: antluba@mail.ru
Russian Federation, Krasnoyarsk, 660041

V. V. Beletskii

Institute of Nonferrous Metals and Materials Science, Siberian Federal University

Email: antluba@mail.ru
Russian Federation, Krasnoyarsk, 660041

N. V. Belousova

Institute of Nonferrous Metals and Materials Science, Siberian Federal University

Email: antluba@mail.ru
Russian Federation, Krasnoyarsk, 660041

V. M. Denisov

Institute of Nonferrous Metals and Materials Science, Siberian Federal University

Email: antluba@mail.ru
Russian Federation, Krasnoyarsk, 660041

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