New copolymer gels based on N,N-dimethylacrylamide and crown-containing allyl derivative of 1,8-naphthalimide as optical sensors for metal cations in an organic medium


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Abstract

New copolymer gels bases on N,N-dimethylacrylamide and a crown-containing allyl derivative of 1,8-naphthalimide showing intense visible fluorescence have been prepared. The effect of metal cations on the optical properties of the fluorescent monomer and its copolymer gels has been studied. These gels have been found to exhibit optical response selectivity with respect to binding of alkaline-earth metals in an acetonitrile medium.

About the authors

M. V. Oshchepkova

Nesmeyanov Institute of Organoelement Compounds; Mendeleev University of Chemical Technology of Russia

Author for correspondence.
Email: margaritamur@gmail.com
Russian Federation, Moscow, 119991; Moscow, 125047

M. S. Oshchepkov

Mendeleev University of Chemical Technology of Russia

Email: margaritamur@gmail.com
Russian Federation, Moscow, 125047

O. A. Fedorova

Nesmeyanov Institute of Organoelement Compounds; Mendeleev University of Chemical Technology of Russia

Email: margaritamur@gmail.com
Russian Federation, Moscow, 119991; Moscow, 125047

Yu. V. Fedorov

Nesmeyanov Institute of Organoelement Compounds

Email: margaritamur@gmail.com
Russian Federation, Moscow, 119991

V. I. Lozinskii

Nesmeyanov Institute of Organoelement Compounds

Email: margaritamur@gmail.com
Russian Federation, Moscow, 119991

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